反应条件
1.1: triethylamine; tetrakis(triphenylphosphine) palladium(0); copper(II) sulfate; sodium L-ascorbate / N,N-dimethyl-formamide / 4 h / 80 °C / |Inert atmosphere; |Darkness 2.1: trifluoroacetic acid / dichloromethane / 2 h / 0 °C 3.1: C21H27AuNP(1+)*F6Sb(1-) / 1,2-dichloro-ethane / 1 h / 45 °C / |Inert atmosphere 3.2: 0.42 h / 0 °C / |Inert atmosphere 4.1: acetic acid / toluene / 4 h / 80 °C / |Inert atmosphere 5.1: boron trifluoride diethyl etherate; tetrachlorosilane / 1,2-dichloro-ethane / 12 h / 20 °C / |Inert atmosphere 5.2: 10 h / 60 °C / |Inert atmosphere 6.1: caesium carbonate / acetone / 3.5 h / 20 °C / |Inert atmosphere 7.1: silver nitrate; water; triethylamine / acetone / 16 h / 50 °C 8.1: water; lithium hydroxide hydrate / tetrahydrofuran / 20 °C 8.2: -78 - -30 °C View Scheme
参考文献
Chiba, Hiroaki; Oishi, Shinya; Fujii, Nobutaka; Ohno, Hiroaki
Angewandte Chemie - International Edition, 2012 , vol. 51, # 36 p. 9169 - 9172