反应条件
carbon oxide sulfide in tetrahydrofuran byproducts: Na2(CO3), Na2(CS3)*H2O; under Ar or N2; adding dry COS to rapidly stirred soln. of Na2(W(CO)5) (-78°C, 30 s), stirring (5 min), settling (25 min); filtering (-78°C), washing (H2O, room temp.), washing (Et2O, -60°C), drying (slow stream of air);
参考文献
Lee, Gary R.; Cooper, N. John
Organometallics, 1989 , vol. 8, p. 1538 - 1544
