tetrahydrofuran in tetrahydrofuran Irradiation (UV/VIS); Ar or N2 atmosphere; irradiation of W(CO)6 in THF soln. (quartz lamp 200 W, 5°C, 4.5 h), add. of PhNO; removal of solvent (standing in argon, 20°C, 20 h), extn. (benzene), chromy. (silica gel, benzene);
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 31, p. 1239 - 1243
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 31, p. 1391 - 1395
in benzene-d6 byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and W complex in C6D6 at 8°C for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
in pentane byproducts: CO; Irradiation (UV/VIS); irradn. of a soln. of W(CO)6 and cyclooctatetraene with a Hg lamp undernitrogen atmosphere at 258 K for 5 h; filtn., removal of the solvent and excess C8H8, column chromy., concg. and cooling of the eluate, drying in high vacuum, elem. anal.;
参考文献
Oezkar, S.; Kreiter, C. G.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1983 , vol. 502, p. 215 - 217
in pentane byproducts: CO; Irradiation (UV/VIS); irradn. of a soln. of W(CO)6 and cyclooctatetraene with a Hg lamp undernitrogen atmosphere at 258 K for more than 5 h; filtn., removal of the solvent and excess C8H8, column chromy., concg. and cooling of the eluate, drying in high vacuum, elem. anal.;
参考文献
Oezkar, S.; Kreiter, C. G.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1983 , vol. 502, p. 215 - 217
in n-heptane Irradiation (UV/VIS); using standard inert atmosphere techniques; W complex reacted with C8H12in n-heptane under photochemical conditions; according to R. B. King, A . Fronzaglia, Inorg. Chem., 1966, 5, 1837-1846; purified by sublimation under vac. at 80°C; detd. by (1)H NMR andIR spectra;
