in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and W complex in C6D6 at 8°C in vac. for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and W complex in C6D6 at 8°C for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and W complex in C6D6 at 8°C for 1 h, standing at room temp. in the dark for 1 d; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and W complex in C6D6 at 8°C for 1 h or irradn. for 1 h, then standing at room temp. for 1 d in the dark; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
pyridine in tetrahydrofuran
byproducts: carbon monoxide; Irradiation (UV/VIS); irradiation (>,= 350 nm) with stirring (72 h), sweeping out CO by N2 passing through; filtration, purification by chromy. (Al2O3, isooctane, benzene, ethanol), recrystn. (benzene/isooctane 1:1); detn. by comparison with UV-vis spectra;
参考文献
Moralejo, Carol; Langford, Cooper H.; Sharma, D. K.
Inorganic Chemistry, 1989 , vol. 28, p. 2205 - 2209
pyridine in tetrahydrofuran
under N2, addn. of TMNO dihydrate to carbonyl-compd. in THF at 28°C, addn. of pyridine after stirring for 10 min, stirred for 3 h at 28°C; evapn. under vac., filtration, recrystn. (CH2Cl2/CH3OH or CH2Cl2/hexane); elem. anal.;
参考文献
Hor, T. S. Andy
Inorganica Chimica Acta, 1988 , vol. 143, p. 3 - 6
