in neat (no solvent) fluorination (N2 carrier gas (ratio F/N2 1:5), -30°C, 2 h);
参考文献
Padma, D K; Kalbandkeri, R G; Suresh, B S; Bhat, V Subrahmanya
Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1991 , vol. 30, # 2 p. 172 - 176
in neat (no solvent) formation on heating to 400 and 500°C with Si in a closed tube; further products;;
参考文献
Barthes, D.; Chaigneau, M.; Malangeau, P.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1968 , vol. 266, p. 1780 - 1783
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Gmelin Handbook: C: MVol.D2, 4.3.2.5.6, page 371 - 372
in neat (no solvent) The halogen was co-condensed in a flask at -196°C with the mixt. of SiF4 and SiF2 emerging out of the reactor tube; further products;; warmed to room temp.; the volatile products were sepd. and detected by NMR and MS;;
参考文献
Suresh, Bettadapura S.; Thompson, James Charlton
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 1123 - 1126
IrradiationCooling with liquid nitrogen; Mechanism;
参考文献
Dementyev, Petr S.; Nizovtsev, Anton S.; Chesnokov, Evgenii N.
Journal of Photochemistry and Photobiology A: Chemistry, 2011 , vol. 222, # 1 p. 77 - 80
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 60 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 60 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
