(E)-1-苯基-2-M-甲苯基乙烯合成路线 （共 48 条）
反应条件
triphenyl-arsane; bis(dibenzylideneacetone)-palladium(0) in toluene T=110°C;
参考文献
Chen, Shu-Hui
Tetrahedron Letters, 1997 , vol. 38, # 27 p. 4741 - 4744
反应条件
AlCl3, aluminium chloride in tetrahydrofuran; 1,4-dioxane T=80°C; 2.16667 h; Inert atmosphereCooling with ice; stereoselective reaction;
参考文献
Peng, Zhi-Yong; Ma, Fang-Fang; Zhu, Lv-Feng; Xie, Xiao-Min; Zhang, Zhaoguo
Journal of Organic Chemistry, 2009 , vol. 74, # 17 p. 6855 - 6858
反应条件
[PdCl2P(OCH2CMe2NH)OCH2CMe2NH2]; tetrabutyl ammonium fluoride in N,N-dimethyl-formamide T=140°C; Hiyama coupling; 4 h; Inert atmosphere;
参考文献
Skarynska, Anna; Majchrzak, Mariusz; Trzeciak, Anna M.; Marciniec, Bogdan
Journal of Molecular Catalysis A: Chemical, 2011 , vol. 351, p. 128 - 135
反应条件
[PdCl2P(OCH2CMe2NH)OCH2CMe2NH2]; tetrabutyl ammonium fluoride in tetrahydrofuran T=60°C; Hiyama coupling; 12 h; Inert atmosphere; diastereoselective reaction;
参考文献
Skarynska, Anna; Majchrzak, Mariusz; Trzeciak, Anna M.; Marciniec, Bogdan
Journal of Molecular Catalysis A: Chemical, 2011 , vol. 351, p. 128 - 135
反应条件
C38H36Cl2Fe2N2Pd2; oxygen in N,N-dimethyl-formamide T=50°C; Heck reaction; 3 h;
参考文献
Leng, Yuting; Yang, Fan; Wei, Kun; Wu, Yangjie
Tetrahedron, 2010 , vol. 66, # 6 p. 1244 - 1248
反应条件
1: triethylamine / CH2Cl2 2: 52 percent / LiCl; isoquinoline / PdCl2 / various solvent(s) / 160 °C View Scheme
参考文献
Goossen, Lukas J.; Paetzold
Angewandte Chemie - International Edition, 2002 , vol. 41, # 7 p. 1237 - 1241
反应条件
1: phenylacetaldehyde With polystyrene-supported 4-(phenylseleno)morpholine in dichloromethane 5 h; Heating; 2: 3-CH3C6H4-MgX T=0 - 20°C; 6 h; 3: With thionyl chloride; triethylamine in dichloromethane T=20°C; 4 h;
参考文献
Sheng, Shou-Ri; Huang, Xian
Journal of the Chinese Chemical Society, 2003 , vol. 50, # 4 p. 893 - 896
反应条件
1: (benzyl)-triphenylphosphonium chloride With n-butyllithium in tetrahydrofuran; hexane T=0°C; Wittig type reaction; 2: 3-Methyl-hydroxymethyl benzene With 4,4'-di-tert-butylbiphenyl; lithium; nickel dichloride in tetrahydrofuran; hexane Wittig type reaction; 8 h; Inert atmosphereReflux; optical yield given as percent de;
参考文献
Alonso, Francisco; Riente, Paola; Yus, Miguel
European Journal of Organic Chemistry, 2009 , # 34 p. 6034 - 6042
反应条件
NiCl2((PPh3)P)2 in tetrahydrofuran 48 h; Ambient temperature;
参考文献
Zhu, Liu-Sheng; Huang, Xian
Synthetic Communications, 1997 , vol. 27, # 1 p. 39 - 44
反应条件
4-Methylpyridine; di-tert-butyl dicarbonate; lithium chloride; palladium dichloride in 1-methyl-pyrrolidin-2-one T=120°C; Heck olefination; 16 h; Title compound not separated from byproducts;
参考文献
Goossen, Lukas J.; Paetzold, Jens; Winkel, Lars
Synlett, 2002 , # 10 p. 1721 - 1723
