顺-3,7-二甲基-2,6-辛二烯-1-醇乙酸酯合成路线 （共 54 条）
反应条件
1: (i) O3, (ii) Me2S
2: Rh(PPh3)3Cl
View Scheme
参考文献
Grieco,P.A.
Journal of the Chemical Society, Chemical Communications, 1972 , p. 486 - 487
反应条件
N-ethyl-N,N-diisopropylamine; triphenylphosphine; sodium bromide; tris(dibenzylideneacetone)dipalladium(0) chloroform complex
T=80°C; P=45600 Torr; 20 h; Yield given. Yields of byproduct given;
参考文献
Murahashi, Shun-Ichi; Imada, Yasushi; Taniguchi, Yuki; Higashiura, Shinya
Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1538 - 1545
反应条件
1: SeO2 / ethanol; pyridine / 1 h / Heating
2: NaBH4 / diethyl ether; methanol / 1 h
3: 79 percent / 1.) 98percent HCOOH; 2.) aq. KOH / 2.5 h / 20 °C
View Scheme
参考文献
Kitagawa, Isao; Tsujii, Shinji; Nishikawa, Fumiko; Shibuya, Hirotaka
Chemical & Pharmaceutical Bulletin, 1983 , vol. 31, # 8 p. 2639 - 2651
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=19°C; 65 h; other acetates, other reagents; Product distribution;
参考文献
Julia, Marc; Nel, Maurice; Righini, Anne; Uguen, Daniel
Journal of Organometallic Chemistry, 1982 , vol. 235, # 1 p. 113 - 120
