(E)-3,7-二甲基-2,6-辛二烯醛合成路线 （共 128 条）
反应条件
1: sodium amalgam; alcohol
View Scheme
参考文献
Zeitschel
Chemische Berichte, 1906 , vol. 39, p. 1782,1784
参考文献
Saucy et al.
Helvetica Chimica Acta, 1959 , vol. 42, p. 1945,1954
反应条件
silica gel; diisobutylaluminium hydride
1.) petroleum ether, hexane, -60 deg C, then 10 deg C over 1.5 h; 2.) petroleum ether, hexane, water, -30 deg C, then 0 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Gebhard, R.; Courtin, J. M. L.; Shadid, J. B.; Haveren, J. van; Haeringen, C. J. van; Lugtenburg, J.
Recueil des Travaux Chimiques des Pays-Bas, 1989 , vol. 108, # 6 p. 207 - 214
反应条件
lithium triethylborohydride; lt;(chlorosulfinyloxy)methylenegt;dimethylammonium chloride; triethylamine; lithium iodide
1.) THF, MeCN, -30 deg C, 1 h, 2.) THF, MeCN, -78 deg C, 15 min; Yield given. Multistep reaction;
参考文献
Khan; Prasada Rao
Journal of Chemical Research - Part S, 1998 , # 7 p. 402 - 403
反应条件
trifluoroacetic acid in 1,3,5-trimethyl-benzene
T=190°C; Claisen-Cope rearrangement; 2 h; Product distribution; Further Variations:Solvents;
参考文献
Nakabayashi, Kazuhiro; Ooho, Masato; Niino, Teppei; Kitamura, Tsugio; Yamaji, Teizo
Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 1 p. 157 - 164
反应条件
1: acetic acid; zinc chloride; toluene-4-sulfonic acid
2: sodium acetate; aqueous acetic acid
View Scheme
参考文献
Samochwalow et al.
Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 2575;engl.Ausg.S.2538
参考文献
Porsch; Farnow
Dragoco Ber., 1959 , vol. 6, p. 248,255
反应条件
sodium acetate; acetic acid
参考文献
Samochwalow et al.
Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 2575;engl.Ausg.S.2538
反应条件
trifluoroacetic acid in 1,3,5-trimethyl-benzene
T=150°C; 0.5 h; Product distribution; Further Variations:ReagentsTemperatures;
参考文献
Nakabayashi, Kazuhiro; Ooho, Masato; Niino, Teppei; Kitamura, Tsugio; Yamaji, Teizo
Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 1 p. 157 - 164
反应条件
in benzene
1 h; Ambient temperature;
参考文献
Takabe, Kunihiko; Yamada, Takashi; Katagiri, Takao
Synthetic Communications, 1983 , vol. 13, # 4 p. 297 - 302
