(E)-3,7-二甲基-2,6-辛二烯醛合成路线 （共 128 条）
反应条件
1.1: BF3*Et2O / CH2Cl2 / 6 h / -78 °C 2.1: 92 percent / imidazole / dimethylformamide / 48 h / 23 °C 3.1: 90 percent / acetic acid / tetrahydrofuran; H2O / 6 h / 50 °C 4.1: n-butyllithium / tetrahydrofuran / -78 °C 4.2: 90 percent / lithium; ethylamine / -78 °C View Scheme
参考文献
Radetich, Branko; Corey
Journal of the American Chemical Society, 2002 , vol. 124, # 11 p. 2430 - 2431
反应条件
hydrogen; H-β zeolite; iridium in isopropyl alcohol T=20°C; P=18001.4 Torr; 2.25 h; Title compound not separated from byproducts;
参考文献
De Bruyn, Mario; Coman, Simona; Bota, Roxana; Parvulescu, Vasile I.; De Vos, Dirk E.; Jacobs, Pierre A.
Angewandte Chemie - International Edition, 2003 , vol. 42, # 43 p. 5333 - 5336
反应条件
H3[PW12O40]; sodium tetrahydroborate in methanol
参考文献
Heydari, Akbar; Khaksar, Samad; Akbari, Jafar; Esfandyari, Maryam; Pourayoubi, Mehrdad; Tajbakhsh, Mahmoud
Tetrahedron Letters, 2007 , vol. 48, # 7 p. 1135 - 1138
反应条件
1: With methyl-diethoxy-silane; Rh<(S,S)-Phebox>(OAc)2(aq) in toluene T=30°C; 1 h; 2: With potassium fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran; methanol; toluene Further stages.;
参考文献
Kanazawa, Yoshinori; Nishiyama, Hisao
Synlett, 2006 , # 19 p. 3343 - 3345
反应条件
hydrogen; naphthalene; chromium tricarbonyl in tetrahydrofuran T=45°C; P=88260.9 Torr; 18 h; other unsaturated compounds, other arene*Cr(CO)3 catalysts, other reaction conditions; Product distributionMechanism;
参考文献
Synthesis, , # 7 p. 643 - 658
反应条件
hydrogen in butan-1-ol T=25°C; P=1140.08 Torr;
参考文献
Wu, Binghui; Huang, Huaqi; Yang, Jing; Zheng, Nanfeng; Fu, Gang
Angewandte Chemie - International Edition, 2012 , vol. 51, # 14 p. 3440 - 3443
反应条件
hydrogen; monoaluminum phosphate; palladium matal-containing silica-supported catalyst in tetrahydrofuran T=29.9°C; P=3102.9 Torr; Ea, ΔH, ΔS; other Pd support, also in the presence of FeCl2; other solvents, var. pressure and temp.; Thermodynamic dataProduct distribution;
参考文献
Aramendia; Borau; Jimenez; Marinas; Porras; Urbano
Journal of Catalysis, 1997 , vol. 172, # 1 p. 46 - 54
反应条件
hydrogen in isopropyl alcohol T=70°C;
参考文献
Bernas, Heidi; Simakova, Irina; Prosvirin, Igor P.; Maeki-Arvela, Paeivi; Leino, Reko; Murzin, Dmitry Yu
Catalysis Letters, 2012 , vol. 142, # 6 p. 690 - 697
反应条件
1: AgNO3/NaOH / H2O; methanol / 0.75 h / 55 - 56 °C 2: H2, NaOCH3, NaClO4 / Rh-6 / methanol / 72 h / 1900 Torr / Ambient temperature; other: catalysts, temps., times, H2 pressures, solvents View Scheme
参考文献
Valentine Jr.; Johnson; Priester; et al.
Journal of Organic Chemistry, 1980 , vol. 45, # 18 p. 3698 - 3703
反应条件
1: NaOH / 2.5 h / Ambient temperature 2: 75 percent / conc. H2SO4 / nitromethane / 0.25 h / 0 °C View Scheme
参考文献
Gebhard, R.; Courtin, J. M. L.; Shadid, J. B.; Haveren, J. van; Haeringen, C. J. van; Lugtenburg, J.
Recueil des Travaux Chimiques des Pays-Bas, 1989 , vol. 108, # 6 p. 207 - 214
