in solid byproducts: C, CO, CH3OH; reaction of equimolar mixt. of NaHCO2 and NaBH4 was carried out in N2 at 0-600°C; quantitative generation of H2 and intermediate adduct BH3*CO2(2-)=(BH3CO2)(2-) described;
参考文献
Gorski, A.; Krasnicka, A. D.
Journal of Thermal Analysis, 1987 , vol. 32, p. 1345 - 1354
in neat (no solvent) passing a vigorous stream of high purity H2 through melting NaHCO2 containing 3percent NaOH at 260-320°C for 1-1.5h; solidification;;
