P-trichloro-N-dichlorophosphoryl-monophosphazene in acetonitrile T=60 - 100°C; KineticsProduct distribution; Further Variations:Solventsalso in the presence of 1,1,3,3,3-pentamethyldisiloxane-1-ol;
参考文献
Phosphorus, Sulfur and Silicon and Related Elements, , vol. 166, p. 283 - 301
water byproducts: C2H5OH; addn. of H2O that contained NaOH to a mixt. of (CH3)2Si(OC2H5)2 and (CH3)3Si(OC2H5) (1:1 mol) at 40°C; boiling after addn. of a 20percent excess of H2O;; evapn. of C2H5OH; distillation gives linear polymers (CH3)3Si((CH3)2SiO)(0-13)Si(CH3)3; higher polymers as residue (not distillable);;
