in neat (no solvent)
byproducts: tributyltin malonate; equimolar mixt. of educts, stirred, 96h, 200°C, distn. under reduced press., acidolysis by addn. of malonic acid in ether, reflux, 48h, ether removed, pptn. of malonate by addn. of pentane, under Ar, further products; ratio of educts I:II:III:IV:VII:VIII=19:17:13:24:7:9, total yield of mixt.: 17percent, alcohols detected by chromy. and silylation followed by IR;
参考文献
Daude, Gerard; Pereyre, Michel
Journal of Organometallic Chemistry, 1980 , vol. 190, # 1 p. 43 - 52
Barr, Philip J.; Jones, A. Stanley; Verhelst, Gabriel; Walker, Richard T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1665 - 1670
Kandiah
Journal of the Chemical Society, 1932 , p. 1215,1226
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Eistert; Geiss
Tetrahedron, 1959 , vol. 7, p. 1,2
Chemische Berichte, 1961 , vol. 94, p. 929,930