环己烯-1-硼酸频哪醇酯合成路线 （共 19 条）
反应条件
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 3 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
反应条件
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 5 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
反应条件
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 16 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
反应条件
RuCl2(tricyclohexylphosphine)2(benzylidene) in benzene room temp., 12 h;
参考文献
Renaud; Ouellet
Journal of the American Chemical Society, 1998 , vol. 120, # 31 p. 7995 - 7996
反应条件
[(2,6-(2,4,6-Me3-C6H2-NdCMe)2C5H3N)Fe(N2)]2(μ2-N2) in neat (no solvent) T=25°C; Inert atmosphere;
参考文献
Organic Letters, , vol. 15, # 11 p. 2680 - 2683
反应条件
C6H5I(CF3CO2); {Pd(C6H3(CH2NMe2)2-2,6)Br} in neat (no solvent) mixt. stirred for 16 h at 20 °C; chromy. on silica gel;
参考文献
Selander, Nicklas; Willy, Benjamin; Szabo, Kaiman J.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 24 p. 4051 - 4053
反应条件
[RhCl(cod)]2; PPh3 in tetrahydrofuran 115°, 12 h, cyclohexene (1.3 mmol), pinacolborane (0.50 mmol), (RhCl(cod))2 (0.013 mmol), PPh3 (10 molpercent), Schlenk tube; 1H NMR;
参考文献
Chemical Communications, , vol. 46, # 6 p. 907 - 909
反应条件
di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium T=70°C; 16 h; Inert atmosphere; regioselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 74, # 20 p. 7715 - 7723
反应条件
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
参考文献
Synthesis, , # 6 p. 778 - 780
反应条件
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
参考文献
Synthesis, , # 6 p. 778 - 780
