17beta-乙酰基-5,6alpha-环氧-5alpha-雄甾烷-3beta-醇乙酸酯合成路线 （共 10 条）
反应条件
oxygen; Ru(VI)(TMP)O2 in benzene T=20°C; 168 h; Title compound not separated from byproducts;
参考文献
Marchon, Jean-Claude; Ramasseul, Rene
Synthesis, 1989 , # 5 p. 389 - 391
反应条件
C26H36F6MnN6O6S2; dihydrogen peroxide; 2-oxo-3,3-dimethyl-butanoic acid in water; ethyl acetate; acetonitrile T=20°C; 1 h; Reagent/catalyst; diastereoselective reaction;
参考文献
Cusso, Olaf; Garcia-Bosch, Isaac; Font, David; Ribas, Xavi; Lloret-Fillol, Julio; Costas, Miquel
Organic Letters, 2013 , vol. 15, # 24 p. 6158 - 6161
反应条件
peracetic acid; sodium acetate
参考文献
Uyanik, Cavit; Malay, Aslihan; Hanson, James R.; Hitchcock, Peter B.; Tiryakioglu, Serpil
Journal of Chemical Research, 2006 , # 7 p. 417 - 419
参考文献
Bowers; Ringold
Journal of the American Chemical Society, 1959 , vol. 81, p. 3710
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Urushibara et al.
Bulletin of the Chemical Society of Japan, 1951 , vol. 24, p. 83
反应条件
ferric picolinate complexes; dihydrogen peroxide in acetonitrile 3 h; Ambient temperature;
参考文献
Kotani, Eiichi; Takeya, Tetsuya; Egawa, Hirotaka; Tobinaga, Seisho
Chemical and Pharmaceutical Bulletin, 1997 , vol. 45, # 4 p. 750 - 752
反应条件
1: peroxybenzoic acid; chloroform View Scheme
参考文献
Ehrenstein; Stevens
Journal of Organic Chemistry, 1941 , vol. 6, p. 908,914
反应条件
perchloric acid; iodine; mercury(II) oxide; N-bromoacetamide 2.) CCl4, irradiation, room temp., 30 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brachet-Cota, Adriana L.; Burton, Gerardo
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1988 , vol. 43, # 4 p. 491 - 496
参考文献
Kirk, David N.; Yeoh, Boon Leng
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 12 p. 2945 - 2952
反应条件
iodine; triphenylphosphine in dichloromethane
参考文献
Paryzek, Zdzislaw; Wydra, Roman
Tetrahedron Letters, 1984 , vol. 25, # 24 p. 2601 - 2604
反应条件
1: CHCl3; THF; HF 2: ether BF3; methanol View Scheme
参考文献
Upjohn Co.
Patent: US2838528 , 1957 ;
