5,10,15,20-四苯基-21H,23H-卟吩钴(II)合成路线 （共 32 条）
反应条件
in neat (no solvent) evapn. deposition of cobalt to monolayer of porphyrin on silver surface; XP spectroscopy;
参考文献
Journal of the American Chemical Society, , vol. 128, # 17 p. 5644 - 5645
反应条件
sodium iodide in chloroform redn. by I(1-) in CHCl3;
参考文献
Inorganic Chemistry, , vol. 25, p. 131 - 135
反应条件
1: propionic acid / 2.25 h / 140 °C / |Inert atmosphere 2: N,N-dimethyl-formamide / 1 h / 110 °C / |Inert atmosphere View Scheme
参考文献
Macromolecules, , vol. 45, # 17 p. 6840 - 6849,10
反应条件
in N,N-dimethyl-formamide two step procedure: absorbing of metal chloride on RB-carbon carrier followed by reaction with porphin;
参考文献
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, , vol. 92, # 11 p. 1403 - 1406
反应条件
sodium tetrahydroborate in methanol; benzene byproducts: H2; Ar-atmosphere; stirring Co-complex with aldehyde and excess of NaBH4 (inC6H6/MeOH=30:1, 10 min); filtration, evapn., washing (MeOH); product mixt. not sepd., detd. by (1)H-NMR spectroscopy; relative yields CHMeCHO:OCHMeCHO:COEt derivatives=8:8:18;
参考文献
Journal of Organometallic Chemistry, , vol. 575, # 1 p. 21 - 32
反应条件
in N,N-dimethyl-formamide free porphyrin metallated with Co acetate in DMF; chromy.(silica gel - chloroform);
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 261, # 2 p. 262 - 266
反应条件
in chloroform; toluene Kinetics; to a stirred soln. of (TPP)Co(III)Cl in CHCl3 is added a soln. of t-BuOOH in toluene, soln. is stirred for 16 h at 30°C; monitored by UV, TLC on silica gel (CHCl3), green fraction and solid green product,recrystn. from CHCl3-heptane, elem. anal.;
参考文献
Inorganic Chemistry, , vol. 25, p. 131 - 135
反应条件
in methanol; dichloromethane stirred for 2 min; evapn. of the solvent, filtn., soln. is treated with NCS, kept in the dark for 24 h at 20°C, filtn., crystn., elem. anal.;
参考文献
Nouveau Journal de Chimie, , vol. 8, p. 759 - 764
反应条件
in perchloric acid; acetonitrile Kinetics; 298 K; not isolated, UV/VIS monitoring (600 - 700nm);
参考文献
Inorganic Chemistry, , vol. 28, p. 2459 - 2465
反应条件
in propionic acid in situ synthesis on RB-carbon support;
参考文献
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, , vol. 92, # 11 p. 1403 - 1406
