(20s)人参皂苷 Rg3合成路线 (共 11 条)
反应条件
H2O (alkaline hydrolysis)
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 31, # 9 p. 3353 - 3356
反应条件
1: 48 mg / diethyl ether / 0.5 h 2: 34 mg / 40percent aqueous AcOH / 3 h / 75 °C 3: 45 mg / KOH / methanol / 0.5 h / 20 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 11 p. 2961 - 2970
反应条件
1: 48 mg / diethyl ether / 0.5 h / Ambient temperature 2: 40 mg / 40percent aqueous AcOH / 3 h / 75 °C 3: 45 mg / KOH / methanol / 0.5 h / 20 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 11 p. 2961 - 2970
反应条件
1: 40 mg / 40percent aqueous AcOH / 3 h / 75 °C 2: 45 mg / KOH / methanol / 0.5 h / 20 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 11 p. 2961 - 2970
反应条件
1: 34 mg / 40percent aqueous AcOH / 3 h / 75 °C 2: 45 mg / KOH / methanol / 0.5 h / 20 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 11 p. 2961 - 2970
反应条件
1: 110 mg / diethyl ether / 0.5 h / 22 °C 2: 104 mg / 40percent aqueous AcOH / 3 h / 75 °C 3: 45 mg / KOH / methanol / 0.5 h / 20 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 11 p. 2961 - 2970
反应条件
1: 104 mg / 40percent aqueous AcOH / 3 h / 75 °C 2: 45 mg / KOH / methanol / 0.5 h / 20 °C View Scheme
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 11 p. 2961 - 2970
反应条件
β-glucosidase in aq. acetate buffer T=32°C; 22 h; Enzymatic reaction;
参考文献
EP2570132 A2, ;
Paragraph 0049; 0050; 0051 ;
反应条件
Eubacterium A-44 in water T=37°C; Product distribution; Further Variations:Reagents;
参考文献
Biological and pharmaceutical bulletin, , vol. 25, # 1 p. 58 - 63
反应条件
β-glucosidase in aq. acetate buffer T=32°C; 22 h; Enzymatic reaction;
参考文献
EP2570132 A2, ;
Paragraph 0049; 0050; 0051 ;