二(2-甲基-2-苯基丙基)二氯化锡合成路线 （共 4 条）
反应条件
NaHSO3; NaOH; HCl in diethyl ether NaHSO3, 10percent NaOH, 10percent HCl;
参考文献
Zimmer,H. et al.
Journal of Organic Chemistry, 1966 , vol. 31, p. 3857 - 3860
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Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.13, page 122 - 129
反应条件
in diethyl ether; toluene 1.44M Et2O soln. of NeophMgCl (1.7-2.05 equiv.) dropwise with stirring added to toluene soln. of SnCl4 (1 equiv.) under N2 at room temp., heatedat reflux for 3 h, left at room temp. for 12 h; aq. satd. soln. NH4Cl added, organic layer separated, aq. layer extracted with Et2O, combined organic extracts dried over MgSO4, solvent removedunder vac., recrystd. from n-heptane; ratio of Nph3SnCl/Nph2SnCl2 was 6 0/40-24.5/75.5, NMR;
参考文献
Zuniga, Adriana E.; Fidelibus, Pablo M.; Mandolesi, Sandra D.; Podesta, Julio C.
Journal of Organometallic Chemistry, 2011 , vol. 696, # 8 p. 1547 - 1555
反应条件
2: NaHSO3; NaOH; HCl / diethyl ether View Scheme
参考文献
Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.13, page 122 - 129
反应条件
in not given according to J. Organomet. Chem. 2011, 696, 1547;
参考文献
Gerbino, Dario C.; Scoccia, Jimena; Koll, Liliana C.; Mandolesi, Sandra D.; Podesta, Julio C.
Organometallics, 2012 , vol. 31, # 2 p. 662 - 671
