1(1R,2R)-(+)-1-苯基亚丙基环氧合成路线 （共 69 条）
反应条件
1: 82.8 percent / pyridinium tosylate / benzene / 14 h / Heating 2: 80 percent / NaI / acetone / 1 h / 50 °C 3: 22 percent / Bu3SnH, AIBN / benzene / Heating 4: 85 percent / LiAlH4, AlCl3 / tetrahydrofuran / 1 h / -78 °C 5: 90 percent / methanol / 15 h / Ambient temperature 6: NaH / dioxane; dimethylformamide / 6 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 48, # 19 p. 3945 - 3960
反应条件
1: 80 percent / NaI / acetone / 1 h / 50 °C 2: 22 percent / Bu3SnH, AIBN / benzene / Heating 3: 85 percent / LiAlH4, AlCl3 / tetrahydrofuran / 1 h / -78 °C 4: 90 percent / methanol / 15 h / Ambient temperature 5: NaH / dioxane; dimethylformamide / 6 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 48, # 19 p. 3945 - 3960
反应条件
1: 22 percent / Bu3SnH, AIBN / benzene / Heating 2: 85 percent / LiAlH4, AlCl3 / tetrahydrofuran / 1 h / -78 °C 3: 90 percent / methanol / 15 h / Ambient temperature 4: NaH / dioxane; dimethylformamide / 6 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 48, # 19 p. 3945 - 3960
反应条件
silver(l) oxide Heating;
参考文献
Cervinka, Otakar; Struzka, Vladimir
Collection of Czechoslovak Chemical Communications, 1990 , vol. 55, # 11 p. 2685 - 2691
反应条件
1: potassium carbonate / methanol / 20 h View Scheme
参考文献
Tetrahedron, , vol. 52, # 13 p. 4593 - 4606
反应条件
1: NaBH4 / methanol / 3 h / 0 - 20 °C 2: potassium carbonate / methanol / 20 h View Scheme
参考文献
Tetrahedron, , vol. 52, # 13 p. 4593 - 4606
反应条件
1: 85 percent / LiAlH4, AlCl3 / tetrahydrofuran / 1 h / -78 °C 2: 90 percent / methanol / 15 h / Ambient temperature 3: NaH / dioxane; dimethylformamide / 6 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 48, # 19 p. 3945 - 3960
反应条件
1: 90 percent / methanol / 15 h / Ambient temperature 2: NaH / dioxane; dimethylformamide / 6 h / Heating View Scheme
参考文献
Tetrahedron, , vol. 48, # 19 p. 3945 - 3960
反应条件
1: triphenylphosphine, iodine, sodium iodide / acetonitrile / 1 h / Heating 2: 1.) CH3)3O+BF4-, 2.) 0.5 N aq. NaOH / 1.) dichloromethane, nitromethane, 0 deg C, 2h, 2.) dichloromethane, 0 deg C, 24 h View Scheme
参考文献
Tetrahedron: Asymmetry, , vol. 2, # 4 p. 257 - 276
反应条件
1: 56 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.5 h / Ambient temperature 2: triphenylphosphine, iodine, sodium iodide / acetonitrile / 1 h / Heating 3: 1.) CH3)3O+BF4-, 2.) 0.5 N aq. NaOH / 1.) dichloromethane, nitromethane, 0 deg C, 2h, 2.) dichloromethane, 0 deg C, 24 h View Scheme
参考文献
Tetrahedron: Asymmetry, , vol. 2, # 4 p. 257 - 276
