1(1R,2R)-(+)-1-苯基亚丙基环氧合成路线 (共 69 条)
反应条件
sodium hydroxide; chloroform; tetrabutyl-ammonium chloride 2 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 25, # 11 p. 1205 - 1208
反应条件
sodium hydroxide; chloroform; tetrabutyl-ammonium chloride 2 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 25, # 11 p. 1205 - 1208
反应条件
chiral polymer-based chromium salen in dichloromethane T=20°C; 12 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 17, # 11 p. 1638 - 1643
反应条件
5,5-methylene di-[(R,R)-{N-(3-tert-butylsalicylidine)-N'-(3',5'-di-tert-butylsalicylidene)}]cyclohexane-1,2-diaminato(2-) Cr(III) chloride in methanol; dichloromethane T=70°C; 0.0333333 h; Microwave irradiation; enantioselective reaction;
参考文献
Chirality, , vol. 19, # 10 p. 809 - 815
反应条件
5,5-methylene di-[(R,R)-{N-(3-tert-butylsalicylidine)-N'-(3',5'-di-tert-butylsalicylidene)}]cyclohexane-1,2-diaminato(2-) Cr(III) chloride in methanol; dichloromethane T=70°C; 0.0333333 h; Microwave irradiation; enantioselective reaction;
参考文献
Chirality, , vol. 19, # 10 p. 809 - 815
反应条件
5,5-methylene di-[(R,R)-{N-(3-tert-butylsalicylidine)-N'-(3',5'-di-tert-butylsalicylidene)}]cyclohexane-1,2-diaminato(2-) Cr(III) chloride in methanol; dichloromethane T=70°C; 0.0333333 h; Microwave irradiation; enantioselective reaction;
参考文献
Chirality, , vol. 19, # 10 p. 809 - 815
反应条件
in benzene T=25°C; 48 h; Yield given;
参考文献
Tetrahedron Letters, , vol. 27, # 42 p. 5079 - 5082
反应条件
RuTTP(THF)2 in benzene-d6 43 h; Ambient temperatureisomerization, stereochemistry; equilibrium concentration of product; Mechanism;
参考文献
Journal of the American Chemical Society, , vol. 110, # 13 p. 4217 - 4220
反应条件
sodium hydroxide; trimethyl-oxonium tetrafluoroborate 1.) dichloromethane, nitromethane, 0 deg C, 2h, 2.) dichloromethane, 0 deg C, 24 h; Yield given. Multistep reaction;
参考文献
Tetrahedron: Asymmetry, , vol. 2, # 4 p. 257 - 276
反应条件
1: 3-chloro-benzenecarboperoxoic acid 2: C68H92Cr2N8O4(2+)*2Cl(1-) / methanol; dichloromethane / 18 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 67, # 43 p. 8300 - 8307