Brown, Douglas G.; Sanguantrakun, Nawaporn; Schulze, Benjamin; Schubert, Ulrich S.; Berlinguette, Curtis P.
Journal of the American Chemical Society, 2012 , vol. 134, # 30 p. 12354 - 12357
1.1: palladium 10 on activated carbon; hydrogen / tetrahydrofuran / 12 h 2.1: acetic acid; sodium nitrite / water / 0 °C 2.2: 0 - 20 °C View Scheme
参考文献
Brown, Douglas G.; Sanguantrakun, Nawaporn; Schulze, Benjamin; Schubert, Ulrich S.; Berlinguette, Curtis P.
Journal of the American Chemical Society, 2012 , vol. 134, # 30 p. 12354 - 12357
Ponomarchuk, M. P.; Kasukhin, L. F.; Shevchenko, M. V.; Sologub, L. S.; Kukhar', V. P.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 11 p. 2468 - 2473,2204 - 2207
trimethylamine
byproducts: (CH3)3N*HCl; HCl elimination with excess of NMe3, react. with MesN3 in situ at -80°C, warming to ambient temp., react. of the formed germaimine with benzaldehyde at 20°C;
参考文献
Riviere-Baudet, M.; Satge, J.; Morere, A.
Journal of Organometallic Chemistry, 1990 , vol. 386, # 1 p. C7 - C11
trimethylamine
byproducts: (CH3)3N*HCl; HCl elimination with excess of NMe3, react. with MesN3 in situ at -80°C, warming to ambient temp., react. of the formed germaimine with nitrone at 20°C;
参考文献
Riviere-Baudet, M.; Satge, J.; Morere, A.
Journal of Organometallic Chemistry, 1990 , vol. 386, # 1 p. C7 - C11
