(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
in tetrahydrofuran under N2 atm. ClAuPPh3 and TlBF4 were added to soln. (NEt4)2(Fe5MoC(CO)17) in THF at -5°C and stirred for 1 h; Et2O was added and mixt. was cooled for 2 h to -30°C, ppt. was filtered, filtrate was evapd. to dryness, residue was extd. with CH2Cl2, hexane was added, soln. was cooled to -30°C overnight; elem. anal.;
参考文献
Reina, Roser; Rodriguez, Laura; Rossell, Oriol; Seco, Miquel; Font-Bardia, Merce; Solans, Xavier
Organometallics, 2001 , vol. 20, # 8 p. 1575 - 1579
反应条件
AgNO3 in dichloromethane byproducts: AgCl; Au(PPh3)Cl was dissolved in CH2Cl2, AgNO3 in methanol was added; AgCl removed by filtration, solution was rotovapped to dryness, extracted with CH2Cl2, filtrated, rotovapped to dryness;
参考文献
Sykes, Andrew G.; Mann, Kent R.
Journal of the American Chemical Society, 1990 , vol. 112, # 20 p. 7247 - 7254
反应条件
PPh3 in dichloromethane; acetonitrile byproducts: TlCl; dissolving Au-complex and PPh3 in mixt. of CH3CN and CH2Cl2, addn. of Tl-compd. in CH3CN; after 2.5 h centrifugation, supernatant removal (reduced pressure), dissolving in dry CH2Cl2, solid crystn. by slow diffusion of dry Et2O;
参考文献
Staples, Richard J.; King, Christopher; Khan, Mohamed N. I.; Winpenny, Richard E. P.; Fackler, John P. Jr
Acta Crystallographica, Section C: Crystal Structure Communications, 1993 , vol. 49, p. 472 - 475
反应条件
NaOMe in methanol; dichloromethane N2-atmosphere; stirring (room temp., 16 h); evapn. (reduced pressure); elem. anal.;
参考文献
Whittall, Ian R.; Humphrey, Mark G.; Houbrechts, Stephan; Persoons, Andre; Hockless, David C. R.
Organometallics, 1996 , vol. 15, # 26 p. 5738 - 5745
反应条件
NaOH in methanol byproducts: NaOCH3; N2, suspn. of ligand (0.44 mmol) and NaOH (4.05 mmol) stirred for 30 min, Au compd. (0.4 mmol) added, stirred for 3 h; filtered off, washed (MeOH, Et2O, pentane), dried (vac.), elem. anal.;
参考文献
Khairul, Wan M.; Albesa-Jove, David; Yufit, Dmitri S.; Al-Haddad, Maha R.; Collings, Jonathon C.; Hartl, Frantisek; Howard, Judith A.K.; Marder, Todd B.; Low, Paul J.
Inorganica Chimica Acta, 2008 , vol. 361, # 6 p. 1646 - 1658
反应条件
Tl(CH3C(O)CHC(O)CH3) in methanol; toluene Tl compd. (1.05 equiv.) was added to suspn. of Au complex in toluene; reacted for 4 h; filtered through Celite; azide was added to filtrate; MeOH was added; stirred for 20 h; filtered through Celite; concd. (vac.); pentane added; elem. anal.;
参考文献
Partyka, David V.; Updegraff III, James B.; Zeller, Matthias; Hunter, Allen D.; Gray, Thomas G.
Organometallics, 2007 , vol. 26, # 1 p. 183 - 186
反应条件
1,2-bis(diphenylphosphino)ethane in ethanol; chloroform addn. of equimolar amt. of dppe (in CHCl3) to Au-complex (in acetone); filtration, concn., crystn. on cooling; elem. anal.;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in tetrahydrofuran Treatment of Mo2W-complex with Au-complex followed by TlPF6, stirring (1 h).; Evapn. of solvent in vac., dissolving in CH2Cl2, column chromy. (Al2O3, CH2Cl2-light petroleum), evapn. in vac., dissolving in min. CH2Cl2, addn. of light petroleum, cooling (-78°C), elem. anal.;
参考文献
Dossett, Stephen J.; Hart, Ian J.; Pilotti, Massimino U.; Stone, F. Gordon A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , p. 3489 - 3498
反应条件
TlPF6 in toluene stirred under N2 for 1.5 h at 0°C then for 1 h at room temp.;; evapd., chromd. on silica gel, eluent hexane;;
参考文献
Ahlgren, Markku; Pakkanen, Tuula T.; Tahvanainen, Ilpo
Journal of Organometallic Chemistry, 1987 , vol. 323, p. 91 - 102
反应条件
in toluene N2, Schlenk techniques, heating in toluene;
参考文献
Journal of Organometallic Chemistry, , vol. 696, # 6 p. 1244 - 1247
