(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
pyridine in not given byproducts: PPh3; N2 atmosphere; pptn.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 907 - 914
反应条件
pyridine in not given byproducts: PPh3; N2 atmosphere; pptn.;
参考文献
Dyson, David B.; Parish, R. V.; McAuliffe, Charles A.; Pritchard, Robin G.; Fields, Roy; Beagley, Brian
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 907 - 914
反应条件
pyridine in not given byproducts: PPh3; N2 atmosphere; pptn.;
参考文献
Dyson, David B.; Parish, R. V.; McAuliffe, Charles A.; Pritchard, Robin G.; Fields, Roy; Beagley, Brian
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 907 - 914
反应条件
pyridine in not given byproducts: PPh3; N2 atmosphere; removal of solvent, triturate with diethyl ether;
参考文献
Dyson, David B.; Parish, R. V.; McAuliffe, Charles A.; Pritchard, Robin G.; Fields, Roy; Beagley, Brian
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 907 - 914
反应条件
in benzene-d6 T=25°C; 0.25 h; Glovebox;
参考文献
Sanagawa, Atsushi; Kuniyasu, Hitoshi; Iwasaki, Takanori; Kambe, Nobuaki; Bobuatong, Karan; Ehara, Masahiro
Chemistry Letters, 2013 , vol. 42, # 8 p. 831 - 832
反应条件
in tetrahydrofuran 4-fluorophenylmagnesium bromide added dropwise at -78°C to soln. ClAuPPh3 in THF in Schlenk techniques under Ar; mixt. warmed to room temp., mixed for 16 h; treated with satd. soln. of NH4Cl, extd. with Et2O; org. layers washed with satd. soln. of NaCl, dried over MgSO4; solvents removed under vac.; crystals obtained via crystn. from CHCl3;
参考文献
Croix; Balland-Longeau; Allouchi; Giorgi; Duchene; Thibonnet
Journal of Organometallic Chemistry, 2005 , vol. 690, # 21-22 p. 4835 - 4843
反应条件
in benzene B2H6 introduced to Ph3PAuCl soln. in benzene at 50°C, after 30-60 min pptd.; filtered, washed with CH2Cl2, dissolved in CH2Cl2, elem. anal.;
参考文献
Schmid, Guenter; Pfeil, Reinhard; Boese, Roland; Bandermann, Friedhelm; Meyer, Sonja; et al.
Chemische Berichte, 1981 , vol. 114, # 11 p. 3634 - 3642
反应条件
in toluene N2, Schlenk techniques, heating in toluene;
参考文献
Meyer, Nadine; Sivanathan, Sivatharushan; Mohr, Fabian
Journal of Organometallic Chemistry, 2011 , vol. 696, # 6 p. 1244 - 1247
反应条件
in benzene-d6 T=25°C; 0.25 h; Glovebox;
参考文献
Sanagawa, Atsushi; Kuniyasu, Hitoshi; Iwasaki, Takanori; Kambe, Nobuaki; Bobuatong, Karan; Ehara, Masahiro
Chemistry Letters, 2013 , vol. 42, # 8 p. 831 - 832
反应条件
in methanol; chloroform; water under N2; to a stirred soln. of Au complex in CHCl3 was added a satd. soln. of NaBr in a mixt. of C2H5OH/H2O, the soln. was stirred for 2 h at 25°C; the solvents was removed by rotary evapn. at -50°C, the residue was extd. with CH2Cl2, the org. layers was dried over Na2CO3, concd., hexane was added to this soln., the mixt. was kept at -30°C;
参考文献
Kronenburg, Claudia M. P.; Jastrzebski, Johann T. B. H.; Boersma, Jaap; Lutz, Martin; Spek, Anthony L.; Van Koten, Gerard
Journal of the American Chemical Society, 2002 , vol. 124, # 39 p. 11675 - 11683
