(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
hydrogen bromide in dichloromethane stream HBr gas passed through stirred soln. triphenylphosphinegold(I) chloride in dichloromethane for 30 min; solvent evapd., residue washed with dichloromethane;
参考文献
Minghetti, Giovanni; Zucca, Antonio; Cinellu, Maria Agostina; Stoccoro, Sergio; Manassero, Mario; Sansoni, Mirella
Journal of Organometallic Chemistry, 1998 , vol. 553, # 1-2 p. 405 - 415
反应条件
in water an excess of aq. KBr;
参考文献
Teets, Thomas S.; Nocera, Daniel G.
Journal of the American Chemical Society, 2009 , vol. 131, p. 7411 - 7420
反应条件
in chloroform-d1 react. of equimolar mixt. under N2 at 30°C and at -13°C; not isolated, 31P-NMR;
参考文献
Attar, Saeed; Nelson, John H.; Bearden, William H.; Alcock, Nathaniel W.; Solujic, Ljiljana; Milosavljevic, Emil B.
Polyhedron, 1991 , vol. 10, p. 1939 - 1950
反应条件
in ethanol in hot EtOH; elem. anal.;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in chloroform-d1 react. of equimolar mixt. under N2 at 30°C; not isolated, 31P-NMR;
参考文献
Attar, Saeed; Nelson, John H.; Bearden, William H.; Alcock, Nathaniel W.; Solujic, Ljiljana; Milosavljevic, Emil B.
Polyhedron, 1991 , vol. 10, p. 1939 - 1950
反应条件
in chloroform-d1 react. of equimolar mixt. under N2 at 30°C; not isolated, 31P-NMR;
参考文献
Attar, Saeed; Nelson, John H.; Bearden, William H.; Alcock, Nathaniel W.; Solujic, Ljiljana; Milosavljevic, Emil B.
Polyhedron, 1991 , vol. 10, p. 1939 - 1950
反应条件
in dichloromethane byproducts: AgCl; (N2); addn. of the Ag-salt to a stirred soln. of the Au-complex in CH2Cl2, stirring for 10 min, filtration from AgCl, addn. of the filtrate to a soln. of the Rh-complex in CH2Cl2; the volume of the soln. is reduced, pptn. by addn. of diethyl ethergive the Au complex, the Rh complex is obtained from the mother liquor, elem. anal.;
参考文献
Inorganic Chemistry, , vol. 31, p. 4797 - 4802
反应条件
PPh3 in tetrahydrofuran; methanol byproducts: AgCl; AgClO4 in MeOH added to soln. of Au-complex in THF; AgCl filtered off; addn. of PPh3 in THF;; solvent removed; recrystn. (CH2Cl2/Et2O);;
参考文献
Deeming, Antony J.; Proud, Graeme P.; Dawes, Helen M.; Hursthouse, Michael B.
Polyhedron, 1988 , vol. 7, p. 651 - 658
反应条件
in dichloromethane byproducts: AgCl; room temp.; molar ratio 1:1, 1 h; filtration off of AgCl, volume reduction, crystn. on Et2O addn.;
参考文献
Laguna, Antonio; Laguna, Mariano; Jimenez, Josefina; Lahoz, Fernando J.; Olmos, Elena
Journal of Organometallic Chemistry, 1992 , vol. 435, # 1.2 p. 235 - 247
反应条件
in cyclohexane soln. Ru3(μ-AuPPh3)(μ-Cl)(CO)10 in cyclohexane refluxed for 24 h under N2 atm.; soln. cooled, solvent removed under vac., mixt. chromed. on silica gel and eluated with toluene-hexane(1-4), yellow fraction - product;
参考文献
Inorganic Chemistry, , vol. 23, p. 609 - 613
