(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
in benzene
T=25°C; 0.5 h; Glovebox;
参考文献
Sanagawa, Atsushi; Kuniyasu, Hitoshi; Iwasaki, Takanori; Kambe, Nobuaki; Bobuatong, Karan; Ehara, Masahiro
Chemistry Letters, 2013 , vol. 42, # 8 p. 831 - 832
参考文献
Gmelin Handbook: V: Org.Verb., 1.1.2, page 3 - 9
反应条件
in diethyl ether
byproducts: Ph3PMe(1+); (N2); addn. of soln. of MeLi in ether to suspn. of gold compd. in ether with stirring at 25.degree, cooling to -75°C, addn. of acetylene deriv., warming to room temp., stirring for 2 h; evapn., extn. (water), dissolving in CH2Cl2, filtration through dry MgSO4, addn. of pentane, NMR;
参考文献
Schuster, Oliver; Schmidbaur, Hubert
Inorganica Chimica Acta, 2006 , vol. 359, # 11 p. 3769 - 3775
反应条件
MeOH in diethyl ether
byproducts: MgCl2; inert atm.; absence of light; cooling (-65°C), stirring (3.5 h), standing overnight (-78°C); filtn., concn. (-40°C), extraction (n-pentane), washing (pentane), drying (vac.);
参考文献
Steinborn, Dirk; Becke, Steffi; Herzog, Renate; Guenther, Mike; Kircheisen, Robert; Stoeckli-Evans, Helen; Bruhn, Clemens
Zeitschrift fur Anorganische und Allgemeine Chemie, 1998 , vol. 624, # 8 p. 1303 - 1307
反应条件
KOH or NaOCH3 in not given
synthesised by reacting Au(triphenylphosphine)Cl with 3-ethynyl-1,10-phenanthroline (1/1 ratio, with an excess KOH or NaOCH3);
参考文献
Yamamoto, Youhei; Shiotsuka, Michito; Okuno, Sigeru; Onaka, Satoru
Chemistry Letters, 2004 , vol. 33, # 3 p. 210 - 211
反应条件
sodium ethanolate in tetrahydrofuran; ethanol
soln. 4-ethynylpyridine and EtONa in EtOH was added to soln. ((PPh3)AuCl) in EtOH-THF (1:1) and stirred at room temp. for 5 h; solvent was evapd. to dryness, residue was recrystd. from CH2Cl2-hexane;elem. anal.;
参考文献
Cheung, Kai-Leung; Yip, Sung-Kong; Yam, Vivian Wing-Wah
Journal of Organometallic Chemistry, 2004 , vol. 689, # 24 SPEC. ISS. p. 4451 - 4462
反应条件
in dichloromethane
T=25°C; 0.166667 h; Inert atmosphere;
参考文献
Kumar, Manish; Jasinski, Jacek; Hammond, Gerald B.; Xu, Bo
Chemistry - A European Journal, 2014 , vol. 20, # 11 p. 3113 - 3119
反应条件
sodium ethanolate in ethanol
a suspn. of complex was treated with NaOEt and the alkyne (bubbled through or added as a liquid) at room temp. or 0°C; filtrn.;
参考文献
Cross, Ronald J.; Davidson, Michael F.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1986 , p. 411 - 414
反应条件
copper(l) chloride in diethylamine
under N2, 0.08 equiv of CuCl was added to stirred mixt. of Au-complex and ligand (molar ratio 1:1.02) in Et2NH, 30 min; solvent removed in vac. at room temp., water added, extd. with benzene,extract dried over MgSO4 overnight, evapd., washed with dry Et2O, recrystd. from toluene-n-octane; elem. anal.;
参考文献
Bruce, Michael I.; Horn, Ernst; Matisons, Janis G.; Snow, Michael R.
Australian Journal of Chemistry, 1984 , vol. 37, # 6 p. 1163 - 1170
反应条件
KOH in methanol; chloroform
byproducts: KCl; KOH soln. in MeOH and carbazole soln. in CHCl3 stirring for 30 min at room temp. under Ar whereupon Au complex soln. in CHCl3 adding, after 30 min of stirring solvent removing in vacuo, residue extg. with CHCl3, KClfiltering off, hexane adding, concg.; identified by elem. anal. and NMR spectrum;
参考文献
Uson, R.; Oro, L. A.; Cabeza, J. A.
Polyhedron, 1984 , vol. 3, p. 497 - 502
