(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
1: tetrahydrofuran; diethyl ether
2: chloroform-d1
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参考文献
Mohr, Fabian; Falvello, Larry R.; Laguna, Mariano
European Journal of Inorganic Chemistry, 2006 , # 4 p. 833 - 838
反应条件
H2O in tetrahydrofuran; methanol
under N2, in darkness, add. of a soln. of AgBF4 in methanol to a soln. of PPh3AuCl in THF, filtration of AgCl, addn of a soln. of 1-azabicyclo(2.2.2)octane in methanol to the filtrate at room temp., stirring for 30 min;
参考文献
Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1992 , vol. 47, # 9 p. 1255 - 1260
反应条件
in methanol
Au-complex added to a stirred soln. of AgBF4, 2 h; evapd. to dryness, extd. with CH2Cl2, Et2O aded, concd., stirred under MeOH overnight, filtered, crystd. twice from CH2Cl2/Et2O, IR, elem. anal.;
参考文献
Banditelli, Guido; Bandini, Anna Laura; Bonati, Flavio; Goel, Ram G.; Minghetti, Giovanni
Gazzetta Chimica Italiana, 1982 , vol. 112, p. 539 - 542
反应条件
in tetrahydrofuran
PH3PAuCl added to AgBF4 in THF, Au-complex in THF added to the mixture with stirring, stirred for 45 min, filtered, added dropwise with stirring to a 1:1 ether-petroleum ether mixture; precipitate separated, washed with ether, dissolved in 1:3 THF-acetone mixture and3:2:1 benzene-ether-hexane mixture added, soln. filtered, filtrate diluted with hexane, left to stand for 8 h at 0°C, washed with ether and pentane;
参考文献
Perevalova, E. G.; Grandberg, K. I.; Baukova, T. V.; Dyadchenko, V. P.; Slovokhotov, Yu. L.; Struchkov, Yu. T.
Sov. J. Coord. Chem. (Engl. Transl.), 1982 , vol. 8, p. 727 - 738
Koordinatsionnaya Khimiya, 1982 , vol. 8, p. 1337 - 1348
反应条件
in tetrahydrofuran
soln. of (Ph3PAu)BF4 obtained from Ph3PAuCl and AgBF4 in THF was added dropwise to soln. of Au complex in THF, mixt. stirred for 45 min, soln. filtered; filtrate was added to ether/petroleum ether, ppt. isolated, washed, dissolved in THF/acetone and benzene/ether/hexane mixt. added, (Ph3PAu)3OBF4pptd, soln. filtered, filtrate dild. with hexane, stored for 8 h at 0°C, washed with ether and pentane;
参考文献
Perevalova, E. G.; Grandberg, K. I.; Dyadchenko, V. P.; Baukova, T. V.
Journal of Organometallic Chemistry, 1981 , vol. 217, # 3 p. 403 - 413
反应条件
in toluene
room temp., N2 atmosphere; addn. of Ag-compd. to soln. of Au-compd. in toluene, stirring (2 h); filtration, washing Au-compd. (CH2Cl2), partial evapn. of washings, pptn. of AgClPPh3 on addn. of hexane;
参考文献
Abu-Salah, Omar M.
Journal of Organometallic Chemistry, 1990 , vol. 387, # 1 p. 123 - 129
反应条件
in diethyl ether
stirred for 2 h at room temp.; filtered off (AgCl(PPh3)), filtrate evapd., addn. of n-hexane, pptn. of (Au(C6F5)(CH2PPh3));
参考文献
Uson, Rafael; Laguna, Antonio; Uson, Alfredo; Jones, Peter G.; Meyer-Baese, Karen
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 341 - 346
反应条件
in acetone
filtn. of Ph3PAgCl, dissoln. of residue in CH2Cl2, pptn. on addn. of hexane;
参考文献
Abu-Salah, O. M.; Al-Ohaly, A. R.; Al-Qahtani, H. A.
Inorganica Chimica Acta, 1986 , vol. 117, p. L29 - L30
反应条件
in tetrahydrofuran
to Ph3PAuCl added AgBF4 in THF, soln. added to Au-complex in THF dropwise, filtered, 1:1 mixture of ether-hexane added dropwise with stirring; separated, washed with ether; elem. anal.;
参考文献
Perevalova, E. G.; Grandberg, K. I.; Baukova, T. V.; Dyadchenko, V. P.; Slovokhotov, Yu. L.; Struchkov, Yu. T.
Sov. J. Coord. Chem. (Engl. Transl.), 1982 , vol. 8, p. 727 - 738
Koordinatsionnaya Khimiya, 1982 , vol. 8, p. 1337 - 1348
反应条件
sodium tetrahydroborate; ethyl stearic acid in chloroform; water
Au(P(C6H5)3)Cl mixed with arachidic acid in CHCl3; soln. deposited onto aq. phase contg. NaBH4 (5E-3 M); solvent evapd.;
参考文献
Khomutov, Gennady B.; Kislov, Vladimir V.; Gainutdinov, Radmir V.; Gubin, Sergey P.; Obydenov, Alexander Yu.; Pavlov, Stanislav A.; Sergeev-Cherenkov, Andrey N.; Soldatov, Eugene S.; Tolstikhina, Alla L.; Trifonov, Artem S.
Surface Science, 2003 , vol. 532-535, p. 287 - 293
