(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
in diethyl ether byproducts: dichloronorcarane; addn. of cyclohexene to soln. of Au-complex;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 12 p. 2506
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 12 p. 2836
反应条件
in not given byproducts: C6H2(OMe2)CH2C(COOMe)2CH2CHCHCH2; react. of Au complex with HCl (in stoich. amounts); detd. by (1)H and (31)P NMR;
参考文献
Angewandte Chemie, International Edition, , vol. 48, p. 5733 - 5736
Angewandte Chemie, , vol. 121, p. 5843 - 5846
反应条件
1: dichloromethane 2: KCl / water; acetone View Scheme
参考文献
Organometallics, , vol. 7, p. 2094 - 2097
反应条件
in chloroform-d1 Sonication; room temp., 2.5 h; chromy. (silica gel) isolation of (Ph3P)AuCl); (1)H-NMR;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 61, p. 3649 - 3652
反应条件
chlorine in not given rapid reaction;
参考文献
Organometallics, , vol. 6, p. 2255 - 2256
反应条件
hydrogenchloride in not given rapid reaction;
参考文献
Organometallics, , vol. 6, p. 2255 - 2256
反应条件
in tetrahydrofuran acetyl chloride added to the Au-complex soln.; solvent evapd. after 12 min; Mn-complex isolated by extn. (petroleum ether), purifn. by chromy. (aluminum oxide, benzene); residue of extn. dissolved in chloroform, chromy.(aluminum oxide); elem. anal.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 54, p. 2424 - 2426
Zhurnal Obshchei Khimii, , vol. 54, p. 2711 - 2714
反应条件
in dichloromethane A soln. of complex in CH2Cl2 was added to a soln. of Au-compound at ca. 20°C; 10 min;; evapd., triturated with C6H6; elem. anal.;;
参考文献
Fontaine, Xavier L. R.; Higgins, Simon J.; Langrick, C. Richard; Shaw, Bernard L.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 777 - 780
反应条件
PPh3 in not given byproducts: BzPh3PCl;
参考文献
Journal of Organometallic Chemistry, , vol. 252, # 2 p. 257 - 262
反应条件
in dichloromethane to soln. of Au(SCN)PPh3 in CH2Cl2 added (Au(C6F5)2Cl)2, stirred for 2 hat room temp.; solid filtered off, extd. with CH2Cl2, concd., hexane added; elem. anal.;
参考文献
Uson, Rafael; Laguna, Antonio; Laguna, Mariano; Abad, Miguel
Journal of Organometallic Chemistry, 1983 , vol. 249, # 3 p. 437 - 444
