(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
in acetone stirring soln. of Au-complex, 1 equiv. of NaClO4*H2O and PPh3 for 3 h atroom temp.; evapn., extn. (CH2Cl2), filtration (MgSO4), concn., pptn. on addn. of Et2O, collection (filtration), drying; elem. anal.;
参考文献
Vicente, Jose; Chicote, Maria Teresa; Lozano, Maria Isabel; Huertas, Sonia
Organometallics, 1999 , vol. 18, # 4 p. 753 - 757
反应条件
in dichloromethane excess of P(C6H5)3 added to soln. of (AuCl(P(C6H5)(CC4H3S)2(C6H8)));
参考文献
Angewandte Chemie - International Edition, , vol. 45, # 37 p. 6152 - 6155
反应条件
in dichloromethane N2 atmosphere, addn. of acac complex to suspension of Au complex, stirring (room temp., 5 h); filtration, concn., pptn. (Et2O), washing (Et2O); elem. anal.;
参考文献
Fernandez, Eduardo J.; Gimeno, M. Concepcion; Jones, Peter G.; Laguna, Antonio; Laguna, Mariano; et al.
Chemische Berichte, 1995 , vol. 128, # 2 p. 121 - 124
反应条件
in acetone byproducts: KCl; mixt. of Au-PPh3 complex and KAuCl4 in acetone was stirred at room temp.for 20 min; concd.; Et2O added; chromd. (silica, 0°C, CH2Cl2); evapd.;
参考文献
Aguilar, David; Contel, Maria; Navarro, Rafael; Urriolabeitia, Esteban P.
Organometallics, 2007 , vol. 26, # 18 p. 4604 - 4611
反应条件
1: methanol 2: CH2Cl2 / dichloromethane View Scheme
参考文献
Inorganic Chemistry, , vol. 24, p. 4298 - 4301
参考文献
Gazzetta Chimica Italiana, , vol. 112, p. 539 - 542
反应条件
triphenylphsophine in not given byproducts: tetrahydrothiophen; a stoich. amt. of PPh3 was used in the reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 247, # 1 p. 105 - 116
反应条件
P(C6H5)3 in not given byproducts: C6H4(CH2NMe2)C6H4(N2Ph); extn. (n-hexane), gas chromy.. mass spectrometry;
参考文献
Journal of Organometallic Chemistry, , vol. 310, p. 401 - 410
反应条件
CH2Cl2 in dichloromethane byproducts: (13)CO2; dissolving Au complex in CH2Cl2; passing stream of CO through soln. for30 min; sealing vessel; mechanism discussed;;
参考文献
Inorganic Chemistry, , vol. 24, p. 4298 - 4301
反应条件
in acetone byproducts: KCl; mixt. of Au-PPh3 complex and KAuCl4 in acetone was stirred at room temp.for 20 min; concd.; Et2O added; chromd. (silica, 0°C, CH2Cl2); evapd.;
参考文献
Aguilar, David; Contel, Maria; Navarro, Rafael; Urriolabeitia, Esteban P.
Organometallics, 2007 , vol. 26, # 18 p. 4604 - 4611
