(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
air in acetone at room temp.;
参考文献
Inorganic Chemistry, , vol. 46, # 21 p. 8939 - 8949
反应条件
in acetonitrile 3-NO2-Hbtsc ligand added to AuCl suspn. in CH3CN (2:1), PPh3 added; filtration, evapn.;
参考文献
Lobana, Tarlok S.; Khanna, Sonia; Butcher, Ray J.
Inorganic Chemistry Communications, 2008 , vol. 11, # 12 p. 1433 - 1435
反应条件
triphenyl-arsane in acetonitrile-D3 T=80°C; 24 h; Inert atmosphereSealed tube;
参考文献
Chemical Communications, , vol. 49, # 65 p. 7246 - 7248
反应条件
chloride in not given excess Cl(1-);
参考文献
New Journal of Chemistry, , vol. 12, p. 505 - 528
反应条件
hydrogenchloride in hydrogenchloride byproducts: phenol; addn. of HCl to soln. of Au-complex, stirring (2 min); solvent removal (vac.), extn. of phenol from solid residue by ether; ppt. dissoln. in chloroform, salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
gold(III) chloride; water in chloroform-d1 0.5 h;
参考文献
Journal of Organometallic Chemistry, , vol. 694, # 4 p. 538 - 545
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: Cl5C6ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (at least 20 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
HCl in chloroform; water 0.1 N HCl added to a soln. of the gold complex in CHCl3; mixt. stirred for 30 min; organic layer sepd. off, washed with water, and dried with K2CO3; CHCl3 removed at reduced pressure;
参考文献
Perevalova, E. G.; Struchkov, Yu. T.; Kravtsov, D. N.; Kuz'mina, L. G.; Smyslova, E. I.; et al.
Journal of General Chemistry USSR (English Translation), 1988 , vol. 58, p. 54 - 61
Zhurnal Obshchei Khimii, 1988 , vol. 58, p. 62 - 71
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: p-FC6H4ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (10 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: o-ClC6H4ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (at least 20 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
