(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: p-FC6H4ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (10 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: o-BrC6H4ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (at least 20 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: p-CH3C6H4ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (10 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: p-NO2C6H4ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (10 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: C6H4(ONa)2; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (10 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
hydrogenchloride; sodium chloride in water; toluene byproducts: F5C6ONa; addn. of satd. aq. soln. of NaCl to soln. of Au-complex (THF), stirring (at least 20 min); addn. of water, titration with HCl; benzene addn., org. layer sepn., washing (water), drying (K2CO3), salting out by petroleum ether;
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.; Struchkov, Yu. T.; Kuz'mina, L. G.; et al.
Sov. J. Coord. Chem. (Engl. Transl.), 1989 , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, 1989 , vol. 15, p. 504 - 523
反应条件
HCl in methanol addn. of HCl to a methanolic soln. of Au-compd.; filtn. of Ph3PAuCl, concn. of mother soln., filtn. of ppt. gives NITRAZEPAM;
参考文献
Inorganica Chimica Acta, , vol. 168, p. 33 - 42
反应条件
in tetrahydrofuran stirring equimolar amts. for 10 min; solvent removal, TLC (Me2CO/petroleum ether=3:7), crystn. (CH2Cl2/MeOH);
参考文献
Bruce, Michael I.; Horn, Ernst; Humphrey, Paul A.; Tiekink, Edward R.T.
Journal of Organometallic Chemistry, 1996 , vol. 518, # 1-2 p. 121 - 138
反应条件
in tetrahydrofuran under N2 atm. suspn. Ir and Au complexes in THF was stirred at room temp. for 6 h; soln. was concd., acetone was added and stirred for 10 min, ppt. was filtered and recrystd. from CHCl3-hexane;
参考文献
Khairul, Wan M.; Fox, Mark A.; Zaitseva, Natasha N.; Gaudio, Maryka; Yufit, Dmitry S.; Skelton, Brian W.; White, Allan H.; Howard, Judith A. K.; Bruce, Michael I.; Low, Paul J.
Dalton Transactions, 2009 , # 4 p. 610 - 620
反应条件
NaOH; H2O in chloroform; water a soln. of the gold complex in CHCl3 is treated with excess of aq. NaCl; Ph3AuCl isolated from the organic layer; NaOH in the aq. layer detd. by titration (HCl);
参考文献
Perevalova, E. G.; Struchkov, Yu. T.; Kravtsov, D. N.; Kuz'mina, L. G.; Smyslova, E. I.; et al.
Journal of General Chemistry USSR (English Translation), 1988 , vol. 58, p. 54 - 61
Zhurnal Obshchei Khimii, 1988 , vol. 58, p. 62 - 71
