(三苯基膦)氯化金(I)合成路线 （共 181 条）
参考文献
Perevalova, E. G.; Smyslova, E. I.; Grandberg, K. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 12 p. 2506
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 12 p. 2836
反应条件
in not given for hours at ambient temp.;
参考文献
Inorganic Chemistry, , vol. 39, # 3 p. 602 - 608
反应条件
in tetrahydrofuran (N2); using Schlenk techniques; treatment of soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in THF with soln. of TiCl3(OCHMe2) (1 equiv.) in THF at -78°C;
参考文献
Organometallics, , vol. 21, # 21 p. 4556 - 4559
反应条件
in dimethylsulfoxide-d6 under N2; react. of gold complex with DCl in CD2Cl2;
参考文献
Dalton Transactions, , p. 951 - 958
反应条件
in acetone under N2 at room temp.;
参考文献
Inorganic Chemistry, , vol. 46, # 21 p. 8939 - 8949
反应条件
in benzene-d6 byproducts: SEt2; (N2); using Schlenk techniques; mixing of PtCl2(SEt2)2 and Au(C6H3(CH2NMe2)2)(PPh3) in 1:1 molar ratio in C6D6; reflux for 2 h; detected by NMR;
参考文献
Organometallics, , vol. 21, # 21 p. 4556 - 4559
反应条件
in dichloromethane-d2 addn. of 3 equiv of triphenylphosphine in CD2Cl2 to a soln. of the Au-Pt complex in CD2Cl2; formation of both complexes in equimolar amts.; extn. of the Pt-complex (acetone), recrystn. (CH2Cl2/pentane), elem. anal.; recrystn. of the Au-complex (CH2Cl2/pentane);
参考文献
Organometallics, , vol. 8, p. 2055 - 2061
反应条件
in not given inert atmosphere; not isolated, detd. by (1)H and (31)P-NMR spectroscopy;
参考文献
Inorganic Chemistry, , vol. 32, p. 3660 - 3669
反应条件
in not given rapid reaction, at -70°C an indermediate complex was formed that izomerized quant. at -10°C; intermediate complex was characterized by NMR spectral data;
参考文献
Organometallics, , vol. 6, p. 2255 - 2256
反应条件
in acetone byproducts: Me2CNH; Au complex (1 equiv.) reacted with Rh complex in acetone;
参考文献
Inorganic Chemistry, , vol. 45, # 1 p. 181 - 188
