1-[4'-(三氟甲基)-4-联苯基]乙酮合成路线 （共 18 条）
反应条件
1: 1-trifluoromethyl-4-bromobenzene With indium; bathophenanthroline; 3-chloroprop-1-ene; lithium chloride; cobalt(II) dibromide in tetrahydrofuran T=100°C; 16 h; Inert atmosphere; 2: 4'-iodoacetophenone With dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate in tetrahydrofuran T=80°C; 18 h; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 18 p. 7563 - 7568
反应条件
alginate/gellan gum beads containing Pd nanoparticles in water T=40°C; Suzuki-Miyaura cross-coupling; 24 h;
参考文献
Green Chemistry, , vol. 14, # 2 p. 317 - 320
反应条件
triphenyl-arsane; lithium chloride; tris-(dibenzylideneacetone)dipalladium(0) in various solvent(s) T=80°C; 70 h;
参考文献
Journal of Organic Chemistry, , vol. 58, # 20 p. 5434 - 5444
反应条件
1: Mg / diethyl ether / Heating 2: 81 percent / aq. NaOH / PdCl2(MeCN)2 / dioxane / 4 h / 80 °C View Scheme
参考文献
Synthesis, , # 15 p. 2231 - 2233
反应条件
N,N,N',N,-tetramethylethylenediamine; α-n-hexadecene; palladium diacetate; di-(1-adamantyl)-n-butylphosphine in toluene T=80°C; Suzuki reaction; P=1875.19 Torr; 24 h; AutoclaveInert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 14, # 12 p. 3645 - 3652
参考文献
WO2004/315 A1, ;
Page 30 ;
WO 2004/000315 A1
反应条件
C37H73N2O16(1+)*I(1-); palladium diacetate; potassium carbonate in water T=99.84°C; Suzuki Coupling; 1 h;
参考文献
Transition Metal Chemistry, , vol. 39, # 2 p. 221 - 224
反应条件
Yield given. Multistep reaction;
参考文献
Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, , vol. 213, p. 187 - 206
