双(三苯基膦)氯化镍(II)合成路线 （共 36 条）
反应条件
in acetone; benzene N2-atmosphere; excess of Co-complex, dissoln. in benzene/acetone=1:1 (50°C), stirring (1 h); crystn. on partial evapn., filtration, evapn. of filtrate to dryness;
参考文献
Sacco, A.; Vasapollo, G.; Giannoccaro, P.
Inorganica Chimica Acta, 1979 , vol. 32, p. 171 - 174
反应条件
in not given dissociation in soln., depending on solvent;
参考文献
Gmelin Handbook: Ni: MVol.C2, 8.18.1, page 1041 - 1052
反应条件
1: Cl2 2: methanol View Scheme
参考文献
Gmelin Handbook: Ni: MVol.C2, 8.18.1, page 1041 - 1052
反应条件
carbon monoxide in tetrahydrofuran
byproducts: NaCl; addn. of n-C4H9ONa to suspn. of Ni compd., CO (40 bar), room temp., 20h, hydrolysis with H2SO4, sepn. of organic phase, dried; yield of organic products detected by chromy.;
参考文献
Hoberg, Heinz; Fananas, F. Javier; Riegel, Hans Josef
Journal of Organometallic Chemistry, 1983 , vol. 254, # 2 p. 267 - 272
反应条件
1: With zinc in ethanol
T=65 - 70°C; 1.5 h;
2: With hydrogenchloride in ethanol; water
T=20 - 25°C; 1 h;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2009/6061 A2, 2009 ;
Location in patent: Page/Page column 28 ;
反应条件
in dichloromethane
T=20°C; 0.166667 h; Inert atmosphereSchlenk technique;
参考文献
Okamoto, Ken; Housekeeper, Jeremy B.; Luscombe, Christine K.
Applied Organometallic Chemistry, 2013 , vol. 27, # 11 p. 639 - 643
