sodium perchlorate in water
Kinetics; Irradiation (UV/VIS); decay of sulfite radical anion at 260 and 280 nm following laser photolysis of Ar satd. 5E-3 mol dm**-3 Na2S2O6 soln. (pH = 1.4 and 4.3) at 193 nm;; not isolated; detection in soln. by optical absorption spectroscopy;;
参考文献
Waygood, Steven J.; McElroy, W. John
Journal of the Chemical Society, Faraday Transactions, 1992 , vol. 88, # 11 p. 1525 - 1530
Dinegar, R. H.; Smellie, R. H.; Mer, V. K. La
Journal of the American Chemical Society, 1951 , vol. 73, p. 2050 - 2054
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Gmelin Handbook: S: MVol.B2, 7.3.3, page 876 - 883
water in water
byproducts: polythionic acids; storage for longer period of time (room temp./CO2 atm./exclusion of air/75 or 500 fold excess of water); reaction discussed;;
参考文献
Noack, E.
Z. Anorg. Chem., 1925 , vol. 146, p. 239 - 262
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
sodium hydroxide; water; cadmium (II) chloride in tetrachloromethane
byproducts: CdS; alkaline hydrolysis; shaking (1-2 min) of S2Cl2 (10E4 -10E3 mol/in CCl4) with excess aq. NaOH (very dild.) in presence of CdCl2; further byproduct: Sμ; mechanism (depending on concns. of educts and temps.) discussed;;
参考文献
Rao, B. S.
Proceedings - Indian Academy of Sciences, Section A, 1939 , vol. 10, p. 423 - 448
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
Bailey, P. L.; Bishop, E.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1973 , p. 917 - 921
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Gmelin Handbook: C: MVol.D3, 6.2.4.7.7.2, page 210 - 210
