in acetonitrile NaBPh4 added to soln. (Pt2(μ-H)2HPt(PEt3)4)(HCO2) in acetonitrile; ppt. filtered, solvent removed under vac., residue dissolved in acetone, methanol added and soln. cooled to -10°C for 48 h; elem. anal.;
参考文献
Paonessa, Ralph S.; Trogler, William C.
Inorganic Chemistry, 1983 , vol. 22, p. 1038 - 1048
in tetrahydrofuran 10-fold excess of (CH2O)n was added to a THF soln. of NaB(C6H5)4 and the resulting suspension was heated at 353 K for 24 h;; residue was washed with THF and ethanol; evapn. of solvent in vac.; colorless solid obtained which was identified by IR, (1)H-NMR, elem. anal.;;
in tetrahydrofuran Kinetics; byproducts: C6H5CHO, C6H5CH2OOCH, CH3OOCH; (CH2O)n was added to a THF (4ml) soln. of NaB(C6H5)4 and the resulting suspension was heated at 353 K in a closed vessel; further products;; periodically monitored by instrumental chromatographic analysis;;
