[(3-甲基-2-丁烯-1-基)氧基]苯合成路线 （共 28 条）
反应条件
sodium hydride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran
T=45°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
sodium hydride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran
T=65°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
sodium hydride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) in tetrahydrofuran
T=45°C; 36 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
sodium hydride; NiCl2(dppb) in tetrahydrofuran
T=65°C; 36 h; Yield given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
2: hydrogen bromide / Endprodukt ist 4-Brom-2-methyl-buten-(2)
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参考文献
Claisen
Journal fuer Praktische Chemie (Leipzig), 1922 , vol. <2> 105, p. 72
Chemische Berichte, 1925 , vol. 58, p. 279 Anm. 15
反应条件
2: hydrogen bromide / dann Umsetzung des erhaltenen 2-Brom-2-methyl-butens-(3)
3: folgend Behandlung des Reaktionsprodukts mit verd. Salzsaeure
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参考文献
Claisen
Journal fuer Praktische Chemie (Leipzig), 1922 , vol. <2> 105, p. 72
Chemische Berichte, 1925 , vol. 58, p. 279 Anm. 15
反应条件
hydrogenchloride in acetic acid
参考文献
Burroughs Wellcome Co.
Patent: US3933820 A1, 1976 ;
反应条件
1: Ca(OCl)2, dry ice / CH2Cl2; H2O / 10 °C
2: ethanol; H2O / Ambient temperature
3: 40 percent peracetic acid, Na2CO3 / CH2Cl2 / 0.5 h
4: ethyl acetate / 0.5 h / 40 - 50 °C
5: MeI / CHCl3 / 3 h / Heating
View Scheme
参考文献
Inoue, Seiichi; Iwase, Norimichi; Miyamoto, Osamu; Sato, Kikumasa
Chemistry Letters, 1986 , p. 2035 - 2038
