trichlorophosphate in chloroform

NiCl2(1,1'-(PPh2)2-ferrocene)2 in diethyl ether 20 h; Ambient temperaturevar. of catalyst; Product distribution;

(S,S)-(chiraphos)NiCl2 in tetrahydrofuran T=20°C; 24 h;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '4267587', constants.ctx, '0')">potassium carbonate</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '635680', constants.ctx, '0')">acetone</a> <br /> <br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '4267587', constants.ctx, '0')">potassium carbonate</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '635680', constants.ctx, '0')">acetone</a> <br />T=50&deg;C;&nbsp;Claisen Rearrangement;&nbsp;&nbsp;Inert atmosphere;&nbsp;&nbsp;Overall yield = 97 percent; Overall yield = 2.88 g;&nbsp;<br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '4122952', constants.ctx, '0')">sodium hydride</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br /> <br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11333866', constants.ctx, '0')">bis(acetylacetonate)nickel(II)</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '906778', constants.ctx, '0')">tris-(dimethylamino)-phosphine</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '969212', constants.ctx, '0')">benzene</a> <br /> <br /> &nbsp;