二甲基[二(2-甲基-1H-茚-1-基)]硅烷合成路线 （共 5 条）
反应条件
1: 2-methyl-indene With n-butyllithium in tetrahydrofuran; toluene T=20 - 80°C; 1 h; 2: dimethyl-dichlorosilane in tetrahydrofuran; toluene T=20 - 60°C;
参考文献
Lammus Novolen Technology GmbH
Patent: US8299287 B2, 2012 ;
Location in patent: Page/Page column 62 ;
反应条件
n-butyllithium in tetrahydrofuran; toluene
参考文献
Mitsubishi Chemical Corporation
Patent: US6255515 B1, 2001 ;
反应条件
1: 2-methyl-indene With n-butyllithium in diethyl ether; hexane T=-20 - 20°C; 2: dimethyl-dichlorosilane in hexane T=-20 - 20°C; Title compound not separated from byproducts;
参考文献
Resconi, Luigi; Camurati, Isabella; Grandini, Cristiano; Rinaldi, Marilisa; Mascellani, Nicoletta; Traverso, Orazio
Journal of Organometallic Chemistry, 2002 , vol. 664, # 1-2 p. 5 - 26
反应条件
1: H2O2 2: H2SO4 3: 2) TosH 4: 1) BuLi / 1) n-hexane, THF, reflux, 1 h , 2) r. t., 15 h View Scheme
参考文献
Spaleck, Walter; Antberg, Martin; Rohrmann, Juergen; Winter, Andreas; Bachmann, Bernd; et al.
Angewandte Chemie, 1992 , vol. 104, # 10 p. 1373 - 1376
反应条件
1: 2) TosH 2: 1) BuLi / 1) n-hexane, THF, reflux, 1 h , 2) r. t., 15 h View Scheme
参考文献
Spaleck, Walter; Antberg, Martin; Rohrmann, Juergen; Winter, Andreas; Bachmann, Bernd; et al.
Angewandte Chemie, 1992 , vol. 104, # 10 p. 1373 - 1376
