(NH4)2Mo2O7 in neat (no solvent) other Radiation; mixt. of O-phthalic anhydride, urea, metal salt and (NH4)2Mo2O7 irradiated in microwave oven at 460W for 8 min. the at 800W for 8 min, cooling to room temp.; washed (H2O, acetone, MeOH, 6M HCl), reflux with acetone, MeOH and CHCl3resp. about 12 h; elem. anal.;

imidazole in N,N-dimethyl acetamide soln. of complex in DMA was degassed, imidazole was added, 10 min; product was not isolated; analyzed by ESR or UV;

I2 in neat (no solvent) tube was loaded with ligand, Mn, I2 and (NH4)6Mo7O24*4H2O under N2, tube was immersed in a 300°C salt bath, after a few min mixt. was solidified, mixt. was left at 300°C for 6 h, cooled; powder was sublimed in a tube furnace in vac. over 2 d at 480°C, crude ppt. was resublimed in vac. at <=460°C (caution: unsublimed material is pyrophoric); elem. anal.;

in not given react. of phthalonitrile with Mn(2+); washing, sublimation;

in not given Irradiation (UV/VIS);

in neat (no solvent) above 180°C;