反应条件
1: 1.) triethylsilane; 2.) 48 percent aq. HF / 1.) (PPh3)3RhCl / 1.) benzene, 70 deg C, 40 min; 2.) CH3CN, rt. 50 min
2: 39 percent / NaBH4 / methanol / 0.75 h / Ambient temperature
3: 85 percent / p-Ts-OH*H2O / benzene / 0.67 h / Ambient temperature
View Scheme
参考文献
Hecker, Scott J.; Heathcock, Clayton H.
Journal of the American Chemical Society, 1986 , vol. 108, # 15 p. 4586 - 4594
