water in water
side reaction of reaction of HClO2 and HClO in weakly acidic or neutral soln. at ambient temp.; excess of ClO(1-); influence of higher temp. and concn.;;
参考文献
White, J. F.; Taylor, M. C.; Vincent, G. P.
Industrial and Engineering Chemistry, 1942 , vol. 34, p. 782 - 792
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Gmelin Handbook: Cl: SVol.B2, 40, page 402 - 404
in water
Kinetics; 0.7-3.0 M chlorite, pH=9-14 (adjusted with NaOH), 15-55°C, in presence if varying amts. of Cl(1-); not isolated, reaction followed by titrimetry and ion exchange chromy.; influence of purity (commercial vs. laboratory chlorite) studied;
参考文献
Adam, Luke C.; Gordon, Gilbert
Inorganic Chemistry, 1999 , vol. 38, # 6 p. 1299 - 1304
in sodium hydroxide
Kinetics; byproducts: Cl(1-); various temps. (40-50°C), excess of ClO2(1-), pH 12.0-13.0, ionic strength 4.00 or 3.79 by adding NaCl;
参考文献
Tasaka, Akimasa; Kimura, Akira; Taguchi, Tomoyuki; Mimoto, Atsuhia
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1989 , p. 174 - 180