1-苯基乙烯基硼酸频哪酯合成路线 （共 16 条）
反应条件
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 5 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
反应条件
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 4 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
反应条件
NaOC(CH3)3; methanol; CuCl(C3H4N2(C10H15)2) in tetrahydrofuran 5.0 molpercent Cu-complex, alkyne, diborane, 5.0 molpercent NaOC(CH3)3, 1.1 equiv CH3OH, THF, 22°C, 12 h, N2 atm.; 98:2 molar ratio of isomers;
参考文献
Jang, Hwanjong; Zhugralin, Adil R.; Lee, Yunmi; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7859 - 7871
反应条件
diisobutylaluminum hydride; [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran 3 molpercent Ni-complex, 1.3 equiv of Al-compound, THF, 0-80°C, 24 h;
参考文献
Gao, Fang; Hoveyda, Amir H.
Journal of the American Chemical Society, 2010 , vol. 132, # 32 p. 10961 - 10963
反应条件
1: phenylacetylene With [RhCl(η2:η2-cycloocta-1,5-diene)]2; benzo[1,3,2]dioxaborole in cyclohexane T=20°C; hydroboration; 2 h; 2: 2,3-dimethylbutane-2,3-diol Substitution; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 122, # 20 p. 4990 - 4991
反应条件
iodine; magnesium in tetrahydrofuran T=25°C; Barbier-type conditions; Inert atmosphere;
参考文献
Clary, Jacob W.; Rettenmaier, Terry J.; Snelling, Rachel; Bryks, Whitney; Banwell, Jesse; Wipke, W. Todd; Singaram, Bakthan
Journal of Organic Chemistry, 2011 , vol. 76, # 23 p. 9602 - 9610
反应条件
methanol; [(N,N′-bis[2,6-diisopropylphenyl]imidazolin-2-ylidene)CuCl]; sodium t-butanolate in tetrahydrofuran T=-15°C; 24 h; Inert atmosphere; regioselective reaction;
参考文献
Jang, Hwanjong; Zhugralin, Adil R.; Lee, Yunmi; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7859 - 7871
反应条件
triethylamine; Rh olefin ligated to 1,3-dimethyl-4-CF3-imidazolylidene in tetrahydrofuran T=25°C; 14 h; Title compound not separated from byproducts.;
参考文献
Tetrahedron, , vol. 64, # 29 p. 6853 - 6862
反应条件
triethylamine; Rh olefin complex ligated to 1,3-dimethyl-imidazolylidene in tetrahydrofuran T=25°C; 14 h; Title compound not separated from byproducts.;
参考文献
Tetrahedron, , vol. 64, # 29 p. 6853 - 6862
反应条件
tris(bicyclo[2.2.1]heptene)palladium; triphenylphosphine T=20°C; 2.5 h;
参考文献
Journal of the Chemical Society, Dalton Transactions, , # 10 p. 1650 - 1656
