platinum in gaseous matrix byproducts: H2, H2O; gauze pretreated in flowing O2 at ambient pressure and 1273 K for 2 h, after evacuation mixt. of O2:Ne (1:1) and (14)NH3:Xe (1:1) pulsed at temps. 1023 and1073 K; monitored at atomic mass units;
参考文献
Perez-Ramirez; Kondratenko; Baerns
Journal of Catalysis, 2004 , vol. 227, # 1 p. 90 - 100
oxygen; platinum in neat (no solvent) Kinetics; byproducts: H2O, N2O, (15)NNO; UHV chamber with (15)NH3 as reducing agent between 428 and 475K and pressures between 1.5E-6 and 6E-5 torr); further byproduct: (15)N2O; not isolated, product ratio determined by mass spectrometry;
参考文献
van Tol; Siera; Cobden; Nieuwenhuys
Surface Science, 1992 , vol. 274, # 1 p. 63 - 81
iridium in neat (no solvent, solid phase) ammonia oxidation studied in situ on Ir(110) and Ir(111) under low-pressure (1E-7 mbar) condition at various temps. (200-700 K);
in gas Kinetics; react. of (15)NH3 and NO in gaseous phase over Co(en)2(NO2)3, ion exchanged into Na-Y-zeolite; further products; not isolated, detected by quadrupole MAS;
参考文献
Naito, Shuichi; Tamaru, Kenzi
Journal of Physical Chemistry, 1983 , vol. 87, # 2 p. 315 - 319
