1: Im / dimethylformamide 2: NaH / tetrahydrofuran 3: Dibal-H / diethyl ether 4: NaH / tetrahydrofuran 5: Dibal-H / diethyl ether 6: n-Bu4NF / tetrahydrofuran 7: MnO2 View Scheme

1: tetrahydrofuran / 0.5 h / 10 °C 2: aluminum isopropoxide / acetone; CH2Cl2 / 5 h / Heating 3: CH2Cl2 / 1 h / Ambient temperature 4: 78 percent / NaOCH3 / CH2Cl2; methanol / 1 h / -10 °C View Scheme

1: TsOH / toluene / Heating 2: Bu3SnH; [PdCl2(PPh3)2]; NH4Cl / H2O; tetrahydrofuran / 3 h View Scheme

1: 95 percent / Bu3SnH 2: 57 percent / Hg(OAc)2 3: N-bromosuccinimide / -20 °C 4: Bu3SnH, AIBN / benzene / 2 h / Heating View Scheme

potassium carbonate in methanol Heating;

potassium hydroxide

Mycobacterium vaccae 10 formate dehydrogenase; sodium formate in aq. phosphate buffer; ethanol T=20°C; pH=6.5; Microbiological reactionEnzymatic reaction;

P386S mutant; sol-gel immobilised P450 BM-3 A74E; NADPH in phosphate buffer; dimethyl sulfoxide pH=7.5; 2 h; Enzymatic reaction;

potassium carbonate; 3-chloro-benzenecarboperoxoic acid 1.) CH2Cl2 2.) MeOH, reflux; Multistep reaction;

Novosphingobium aromaticivorans DSM12444 [2Fe-2S] ferredoxin; Novosphingobium aromaticivorans DSM12444 cytochrome P450 101C1; Novosphingobium aromaticivorans DSM12444 oxygenase-coupled NADH-dependent ferredoxin reductase; oxygen; Reduced nicotinamide-adenine dinucleotide; bovine liver catalase in ethanol; tri-(hydroxymethyl)-methylamine T=30°C; pH=7.4; Enzymatic reaction; Kinetics;