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结构式
乙二醇
甲醛
63148-62-9
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丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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14399-53-2
合成路线
（共 27 条）
75-11-6
二碘甲烷
+
557-20-0
二乙基锌
→
反应条件
14399-53-2
反应条件
in dichloromethane at 65°C; not isolated;
参考文献
Denmark, Scott E.; Edwards, James P.; Wilson, Scott R.
Journal of the American Chemical Society, 1991 , vol. 113, # 2 p. 723 - 725
563-79-1
2,3-二甲基-2-丁烯
+
14399-53-2
→
反应条件
4127-47-3
1,1,2,2-四甲基环丙烷
反应条件
暂无反应条件数据
参考文献
Wittig,G.; Wingler,F.
Chemische Berichte, 1964 , vol. 97, p. 2146 - 2164
95126-91-3
+
14399-53-2
→
反应条件
622-97-9
4-甲基苯乙烯
反应条件
1: 1-methyl-4-(4-methylbenzylsulfinyl)benzene With lithium diisopropyl amide in tetrahydrofuran T=-70 - -40°C; 2: With copper(I) bromide in tetrahydrofuran T=-40 - 20°C; 0.5 h; 3: Zn(CH2I)2 in tetrahydrofuran T=20°C; 1 h;
参考文献
Organic Letters, , vol. 6, # 4 p. 621 - 623
14399-53-2
+
180746-15-0
→
反应条件
637-69-4
4-甲氧基苯乙烯
反应条件
1: 1-methoxy-{[(4-methylphenyl)sulfinyl]methyl}benzene With lithium diisopropyl amide in tetrahydrofuran T=-70 - -40°C; 0.5 h; 2: With copper(I) bromide in tetrahydrofuran T=-40 - 20°C; 0.5 h; 3: Zn(CH2I)2 in tetrahydrofuran T=20°C; 1 h;
参考文献
Abramovitch, Adi; Marek, Ilan
European Journal of Organic Chemistry, 2008 , # 29 p. 4924 - 4931
14399-53-2
+
120982-92-5
→
反应条件
768-56-9
4-苯基-1-丁烯
反应条件
1: 1-methyl-4-(3-phenylpropylsulfinyl)benzene With lithium diisopropyl amide in tetrahydrofuran T=-70 - -40°C; 2: With copper(I) bromide in tetrahydrofuran T=-40 - 20°C; 0.5 h; 3: Zn(CH2I)2 in tetrahydrofuran T=20°C; 1 h;
参考文献
Abramovitch, Adi; Marek, Ilan
European Journal of Organic Chemistry, 2008 , # 29 p. 4924 - 4931
645-49-8
顺式-二苯乙烯
+
14399-53-2
→
反应条件
29881-14-9
1,2-二苯基环丙烷
反应条件
1: Zn(CH2I)2 With ethylene glycol dimethyl ether; trichloroacetic acid in hexane; dichloromethane T=-15°C; Simmons-Smith Cyclopropanation; 1 h; Schlenk techniqueInert atmosphere; 2: meso-1,2-diphenylethylene in hexane; dichloromethane T=-15 - 25°C; Simmons-Smith Cyclopropanation; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Cheng, Donghao; Huang, Deshun; Shi, Yian
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 34 p. 5588 - 5591
103-30-0
反式-1,2-二苯乙烯
+
14399-53-2
→
反应条件
29881-14-9
1,2-二苯基环丙烷
反应条件
1: Zn(CH2I)2 With ethylene glycol dimethyl ether; trichloroacetic acid in hexane; dichloromethane T=-15°C; Simmons-Smith Cyclopropanation; 1 h; Schlenk techniqueInert atmosphere; 2: (E)-1,2-diphenyl-ethene in hexane; dichloromethane T=-15 - 30°C; Simmons-Smith Cyclopropanation; Schlenk techniqueInert atmosphere; Reagent/catalystSolvent;
参考文献
Cheng, Donghao; Huang, Deshun; Shi, Yian
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 34 p. 5588 - 5591
14399-53-2
+
142-29-0
环戊烯
→
反应条件
285-58-5
双环[3.1.0]己烷
反应条件
暂无反应条件数据
参考文献
Wittig,G.; Wingler,F.
Chemische Berichte, 1964 , vol. 97, p. 2146 - 2164
766-90-5
顺-β-甲基苯乙烯
+
14399-53-2
→
反应条件
3145-76-4
1-甲基-2-苯基环丙烷
反应条件
1: Zn(CH2I)2 With ethylene glycol dimethyl ether; trichloroacetic acid in hexane; dichloromethane T=-15°C; Simmons-Smith Cyclopropanation; 1 h; Schlenk techniqueInert atmosphere; 2: cis-β-methylstyrene in hexane; dichloromethane T=-15 - 25°C; Simmons-Smith Cyclopropanation; 18 h; Schlenk techniqueInert atmosphere;
参考文献
Cheng, Donghao; Huang, Deshun; Shi, Yian
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 34 p. 5588 - 5591
873-66-5
甲基苯乙烯
+
14399-53-2
→
反应条件
3145-76-4
1-甲基-2-苯基环丙烷
反应条件
1: Zn(CH2I)2 With ethylene glycol dimethyl ether; trichloroacetic acid in hexane; dichloromethane T=-15°C; Simmons-Smith Cyclopropanation; 1 h; Schlenk techniqueInert atmosphere; 2: trans-2-methylstyrene in hexane; dichloromethane T=-15 - 25°C; Simmons-Smith Cyclopropanation; 18 h; Schlenk techniqueInert atmosphere;
参考文献
Cheng, Donghao; Huang, Deshun; Shi, Yian
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 34 p. 5588 - 5591
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