ammonium hydroxide Ar; a mixture of the starting complex and NH4OH was refluxed for 25 min; addn. of Ca(SO3)2; isoln. of (OH)(NH3)5Ru(SO3)2at 0° C; dissoln. in oxalic acid; reflux for 5 min; isolation of the oxalato-intermediate; reflux of a HCl-soln. for 10 min;; hot filtration; addn. of ethanol to the filtrate; cooling overnight at 0 ° C; filtration; recrystn. from warm 8 M HCl/ethanol; chilling at 0 ° C for 8 h;;
参考文献
Salaymeh, Faleh; Berhane, Samson; Yusof, Rohana; Rosa Roger de la; Fung, Ella Y.; et al.
Inorganic Chemistry, 1993 , vol. 32, p. 3895 - 3908
water und Erwaermen des Reaktionsprodukts mit wss. K2CO3;
参考文献
Wang, Ruihu; Xu, Hongyan; Guo, Yong; Sa, Rongjian; Shreeve, Jean'ne M.
Journal of the American Chemical Society, 2010 , vol. 132, # 34 p. 11904 - 11905
