2-甲基-6-亚甲基-2,7-辛二烯-4-醇合成路线 （共 26 条）
反应条件
diisobutylaluminium hydride in benzene
参考文献
Sakurai, Hideki; Hosomi, Akira; Saito, Masaki; Sasaki, Koshi; Iguchi, Hirokazu; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 883 - 894
反应条件
zinc in N,N-dimethyl-formamide
T=0°C; 2 h;
参考文献
Tokuda, Masao; Mimura, Nobuo; Karasawa, Tamae; Fujita, Hirotake; Suginome, Hiroshi
Tetrahedron Letters, 1993 , vol. 34, # 47 p. 7607 - 7610
反应条件
potassium hydroxide in methanol
3 h; Ambient temperature;
参考文献
Baeckstroem, P.; Bjoerkling, F.; Hoegberg, H.-E.; Norin, T.
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 1 p. 1 - 6
反应条件
1: (2-methyl-1-propenyl)carbonyl chloride With AlCl3, aluminium chloride in dichloromethane
T=-60°C; Inert atmosphere;
2: Dimethyl-(2-methylene-but-3-enyl)-phenyl-silane in dichloromethane
T=-60°C; 0.25 h; Inert atmosphere; Further stages;
参考文献
Pulido, Francisco J.; Barbero, Asuncion; Garcia, Carlos
Tetrahedron, 2009 , vol. 65, # 28 p. 5535 - 5540
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
T=35°C; 2 h;
参考文献
Sakurai, Hideki; Hosomi, Akira; Saito, Masaki; Sasaki, Koshi; Iguchi, Hirokazu; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 883 - 894
反应条件
ethylene dibromide; copper(I) bromide; lithium bromide; zinc in tetrahydrofuran; ethanol
1 h; Heating;
参考文献
Klusener, Peter A. A.; Kulik, Willem; Brandsma, Lambert
Journal of Organic Chemistry, 1987 , vol. 52, # 23 p. 5261 - 5266
反应条件
1: AlCl3 / CH2Cl2 / 0.25 h / -60 °C
2: DIBAH / toluene / 4 h / -40 - 0 °C
View Scheme
参考文献
Barbero; Garcia; Pulido
Synlett, 2001 , # 6 p. 824 - 826
反应条件
triethanolamine
0.5 h; from -70 to 0 degC;
参考文献
Bubnov, Yu. N.; Etinger, M. Yu.; Ignatenko, A. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 6.2 p. 1226 - 1233
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , # 6 p. 1343 - 1351
反应条件
1: 54 percent / N-bromosuccinimide, dibenzoyl peroxide / CCl4 / 2 h / Heating
2: 90 percent Spectr. / Zn powder / tetrahydrofuran / 1.) reflux, 2 h; 2.) room. temp., 2 h
View Scheme
参考文献
Tokuda; Mimura; Yoshioka; Karasawa; Fujita; Suginome
Synthesis, 1993 , # 11 p. 1086 - 1088
反应条件
1: ethylaluminum dichloride / CH2Cl2 / 1 h / -20 °C
2: sodium borohydride / propan-2-ol; H2O / 4.5 h / 20 °C
View Scheme
参考文献
Snider, Barry B.; Jackson, Andrew C.
Journal of Organic Chemistry, 1982 , vol. 47, # 27 p. 5393 - 5395
