(S)-(-)-1-苯基乙醇合成路线 （共 393 条）
反应条件
chiral 2-(3',5'-di-tert-butylphenyl)-4,4,8-trimethyl-2-phosphabicylolt;3.3.0gt;octane in n-heptane 1 h; Ambient temperatureother catalyst; var. temp.; other carbinols; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 121, # 24 p. 5813 - 5814
反应条件
Rhodotorula rubra; hydrogen; sodium lauryl sulfate in phosphate buffer T=30°C; Reduction; 30 h; Title compound not separated from byproducts;
参考文献
Goswami; Bezbaruah; Borthakur; Dey; Hazarika
Tetrahedron Asymmetry, 2000 , vol. 11, # 18 p. 3701 - 3709
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 96 h;
参考文献
Journal of Organic Chemistry, , vol. 69, # 6 p. 1972 - 1977
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 72 h;
参考文献
Journal of Organic Chemistry, , vol. 69, # 6 p. 1972 - 1977
反应条件
titanium tetrachloride; 2,2'-[trans-(R,R)-1,2-cyclohexanediylbis(N-methylaminomethyl)]-diphenol in dichloromethane T=-60°C; 72 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 16, # 3 p. 605 - 608
反应条件
Candida antarctica lipase B in diethyl ether T=20°C; 140 h; Enzymatic reaction; optical yield given as percent ee;
参考文献
Tetrahedron Asymmetry, , vol. 20, # 10 p. 1191 - 1196
反应条件
hydrogen; potassium hydroxide; epi.-Cin.-NH2 in isopropyl alcohol T=40°C; P=45004.5 Torr; 3 h; Autoclave; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 11, # 7 p. 584 - 587
反应条件
Rhodium trichloride; C45H48N4O4S2; hydrogen; sodium hydroxide in methanol T=40°C; P=37503.8 Torr; 48 h; Inert atmosphere; optical yield given as percent ee;
参考文献
Tetrahedron Letters, , vol. 50, # 6 p. 688 - 692
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran T=20°C; 10 h; Inert atmosphere; optical yield given as percent ee;
参考文献
Organic Letters, , vol. 13, # 15 p. 3794 - 3797
反应条件
(R)-(+)-N-methylbenzoguanidine; trimethylacetic anhydride in diethyl ether T=20°C; 12 h; Resolution of racemate; optical yield given as percent ee;
参考文献
Nakata, Kenya; Shiina, Isamu
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 20 p. 7092 - 7096
