(S)-(-)-1-苯基乙醇合成路线 （共 393 条）
反应条件
(5aS,10bR)-5a,10b-dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate; 3-benzylriboflavin tetraacetate; triethylamine in toluene T=20°C; 4 h; Resolution of racemateAirMolecular sieve; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 29 p. 8009 - 8013
反应条件
(5aS,10bR)-5a,10b-dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate; 3-benzylriboflavin tetraacetate; triethylamine in toluene T=20°C; 19 h; Resolution of racemateAirMolecular sieve; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 29 p. 8009 - 8013
反应条件
(-)-Tetramisole; N-ethyl-N,N-diisopropylamine in chloroform T=0°C; 13 h; Inert atmosphere; optical yield given as percent ee;
参考文献
Journal of Organic Chemistry, , vol. 77, # 7 p. 3570 - 3575
反应条件
lipase B from Candida antarctica in toluene T=78°C; 48 h; Enzymatic reaction;
参考文献
European Journal of Organic Chemistry, , vol. 2014, # 14 p. 2917 - 2923
参考文献
Noe, Christian R.; Knollmueller, Max; Wagner, Ernst; Voellenkle, Horst
Chemische Berichte, 1985 , vol. 118, # 5 p. 1733 - 1745
反应条件
tetrabutyl ammonium fluoride T=23°C; 3 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 7, # 1 p. 69 - 78
反应条件
potassium hydroxide; dihydrogen peroxide in tetrahydrofuran; ethanol; water 1 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron, , vol. 53, # 33 p. 11411 - 11424
反应条件
Na-Pi buffer in acetone 48 h; tubers of Helianthus tuberosus presence, pH 5.9; other biologically active material: tubers of Solanum tuberosum cv. Saturna; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mironowicz, Agnieszka
Phytochemistry, 1998 , vol. 47, # 8 p. 1531 - 1534
反应条件
chiral osmaimidazolidine ligand; titanium(IV) isopropylate in toluene T=-30°C; Product distribution; Further Variations:CatalystsReaction partners;
参考文献
Tetrahedron Letters, , vol. 44, # 17 p. 3547 - 3549
反应条件
phosphate buffer; almond-β-glucosidase T=37°C; pH=6.0; 24 h; Enzymatic reaction; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 15, # 15 p. 2319 - 2321
