[(三甲基硅烷基)甲基]膦酸二乙酯合成路线 （共 25 条）
反应条件
1: 1) n-BuLi / 1) THF, 1 h, RT; 2) warming from -78 deg C to RT
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参考文献
Porskamp, Pascal A. T. W.; Lammerink, Ben H. M.; Zwanenburg, Binne
Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 263 - 268
反应条件
1: 1) n-BuLi / 1) THF, 1 h, RT; 2) warming from -78 deg C to RT
3: 1.) thallous ethoxide / 1) benzene, 1.5 h, roomtemp.; 2) 1 h, roomtemp.
View Scheme
参考文献
Porskamp, Pascal A. T. W.; Lammerink, Ben H. M.; Zwanenburg, Binne
Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 263 - 268
反应条件
1: 1.) n-BuLi / 1.) hexane, THF, -78 deg C, 2.) -78 deg C
2: 72 percent Spectr. / 3-chloroperoxybenzoic acid / CCl4 / 1.) 0 deg C, 15 min, 2.) room temp., 30 min
3: H2O / CCl4
View Scheme
参考文献
Mikolajczyk, Marian; Balczewski, Piotr
Synthesis, 1989 , # 2 p. 101 - 106
反应条件
(i) nBuLi, THF, hexane, (ii) /BRN= 635680/; Multistep reaction;
参考文献
Carey,F.A.; Court,A.S.
Journal of Organic Chemistry, 1972 , vol. 37, p. 939 - 943
反应条件
1: 1.) n-BuLi / 1.) hexane, THF, -78 deg C, 2.) -78 deg C
2: 1.) n-BuLi / 1.) Et2O, THF, -78 deg C, 10 min, 2.) room temp., 1 h; reflux, 30 min
View Scheme
参考文献
Mikolajczyk, Marian; Balczewski, Piotr
Synthesis, 1989 , # 2 p. 101 - 106
