2-羟基-5-甲基苯乙酮合成路线 （共 181 条）
反应条件
anhydrous sodium benzoate
T=180 - 210°C;
参考文献
Jain, P. K.; Makrandi, J. K.; Grover, S. K.
Synthesis, 1982 , # 3 p. 221 - 222
反应条件
1: sodium hydroxide / ethanol / 20 °C
2: copper(l) iodide; oxygen / 48 h / 50 °C / 760.05 Torr / Ionic liquid
View Scheme
参考文献
Du, Zhiyun; Ng, Huifen; Zhang, Kun; Zeng, Huaqiang; Wang, Jian
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 20 p. 6930 - 6933
反应条件
anhydrous sodium benzoate
T=190°C;
参考文献
Robertson; Sandrock
Journal of the Chemical Society, 1932 , p. 1180,1182
反应条件
1: pyridine
2: 85percent KOH / pyridine / Heating
3: sulfuric acid, glacial acetic acid
4: 100 percent / dimethyldioxirane / acetone; CH2Cl2 / 23 h / 0 °C
5: 100 percent / CDCl3 / 12 h / Ambient temperature
View Scheme
参考文献
Pendse; Limaye
Rasayanam, 1955 , vol. 2, p. 74,78
反应条件
sodium hydroxide
unter Zutritt von Luft;
参考文献
Limaye; Limaye
Rasayanam, 1952 , vol. 2, p. 41,44
反应条件
1.1: pyridine
2.1: KOH / pyridine
3.1: AcOH; H2SO4
4.1: PhI(OAc)2; KOH / methanol
4.2: HCl / acetone
View Scheme
参考文献
Kline; Fromhold; McKennon; Cai; Treiberg; Ihle; Sherman; Schwan; Hickey; Warrener; Witte; Brody; Goltry; Barker; Anderson; Tanaka; Shawar; Nguyen; Langhorne; Bigelow; Embuscado; Naeemi
Bioorganic and Medicinal Chemistry, 2000 , vol. 8, # 1 p. 73 - 93
反应条件
1: potassium hydroxide / ethanol / 15 h / 50 °C
2: dihydrogen peroxide; sodium hydroxide / methanol / 15 h / 20 °C
View Scheme
参考文献
Ravichandran; Singh; Donnelly; Migliore; Johnson; Fishwick; Luke; Martin; Maudsley; Fugmann; Moaddel
Journal of Molecular Graphics and Modelling, 2014 , vol. 49, p. 38 - 46
参考文献
King; McWhirter; Barton
Journal of the American Chemical Society, 1945 , vol. 67, p. 2089,2090
参考文献
King; McWhirter; Barton
Journal of the American Chemical Society, 1945 , vol. 67, p. 2089,2090
反应条件
sulfur in water
T=100°C; 8 h;
参考文献
Kuliev, A. B.; Anave, P. A. L.; Kuliev, F. A.; Mamedova, Sh. E.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 1493 - 1494
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1709 - 1711
